Phosphonic acids aid composition adjustment in the synthesis of Cu2+xZn1−xSnSe4−y nanoparticles

M. Ibáñez, T. Berestok, O. Dobrozhan, A. Lalonde, V. Izquierdo Roca, A. Shavel, A. Pérez Rodríguez, G.J. Snyder, A. Cabot, Journal of Nanoparticle Research 18 (2016).

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Journal Article | Published | English
Author
Ibanez Sabate, MariaIST Austria ; Berestok, Taisiia; Dobrozhan, Oleksandr; Lalonde, Aaron; Izquierdo Roca, Victor; Shavel, Alexey; Pérez Rodríguez, Alejandro; Snyder, G Jeffrey; Cabot, Andreu
Abstract
The functional properties of quaternary I2–II–IV–VI4 nanomaterials, with potential interest in various technological fields, are highly sensitive to compositional variations, which is a challenging parameter to adjust. Here we demonstrate the presence of phosphonic acids to aid controlling the reactivity of the II element monomer to be incorporated in quaternary Cu2ZnSnSe4 nanoparticles and thus to provide a more reliable way to adjust the final nanoparticle metal ratios. Furthermore, we demonstrate the composition control in such multivalence nanoparticles to allow modifying charge carrier concentrations in nanomaterials produced from the assembly of these building blocks.
Publishing Year
Date Published
2016-08-11
Journal Title
Journal of Nanoparticle Research
Volume
18
Issue
8
IST-REx-ID
367

Cite this

Ibáñez M, Berestok T, Dobrozhan O, et al. Phosphonic acids aid composition adjustment in the synthesis of Cu2+xZn1−xSnSe4−y nanoparticles. Journal of Nanoparticle Research. 2016;18(8). doi:10.1007/s11051-016-3545-4
Ibáñez, M., Berestok, T., Dobrozhan, O., Lalonde, A., Izquierdo Roca, V., Shavel, A., … Cabot, A. (2016). Phosphonic acids aid composition adjustment in the synthesis of Cu2+xZn1−xSnSe4−y nanoparticles. Journal of Nanoparticle Research, 18(8). https://doi.org/10.1007/s11051-016-3545-4
Ibáñez, Maria, Taisiia Berestok, Oleksandr Dobrozhan, Aaron Lalonde, Victor Izquierdo Roca, Alexey Shavel, Alejandro Pérez Rodríguez, G Jeffrey Snyder, and Andreu Cabot. “Phosphonic Acids Aid Composition Adjustment in the Synthesis of Cu2+xZn1−xSnSe4−y Nanoparticles.” Journal of Nanoparticle Research 18, no. 8 (2016). https://doi.org/10.1007/s11051-016-3545-4.
M. Ibáñez et al., “Phosphonic acids aid composition adjustment in the synthesis of Cu2+xZn1−xSnSe4−y nanoparticles,” Journal of Nanoparticle Research, vol. 18, no. 8, 2016.
Ibáñez M, Berestok T, Dobrozhan O, Lalonde A, Izquierdo Roca V, Shavel A, Pérez Rodríguez A, Snyder GJ, Cabot A. 2016. Phosphonic acids aid composition adjustment in the synthesis of Cu2+xZn1−xSnSe4−y nanoparticles. Journal of Nanoparticle Research. 18(8).
Ibáñez, Maria, et al. “Phosphonic Acids Aid Composition Adjustment in the Synthesis of Cu2+xZn1−xSnSe4−y Nanoparticles.” Journal of Nanoparticle Research, vol. 18, no. 8, Springer, 2016, doi:10.1007/s11051-016-3545-4.

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