Binary Polyethylene Oxide/Titania Solid-State Redox Electrolyte for Highly Efficient Nanocrystalline TiO2 Photoelectrochemical Cells

T. Stergiopoulos, I. Arabatzis, G. Katsaros, P. Falaras, Nano Letters 2 (2002) 1259–1261.

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Abstract
Poly(ethylene oxide)/titania polymer electrolyte based photoelectrochemical cells have been fabricated with Ru(dcbpy)2(NCS)2 complex as the sensitizer and nanoporous TiO2 films as photoanodes. The introduction of the titania filler into the poly(ethylene oxide) matrix reduces the crystallinity of the polymer and enhances the mobility of the 1-/13 - redox couple, resulting in outstanding overall conversion efficiency (4.2% under direct sunlight illumination) of the corresponding dye-sensitized nanocrystalline TiO2 solar cell, one of the best efficiencies reported to date for a solid-state device.
Publishing Year
Date Published
2002-11-01
Journal Title
Nano Letters
Acknowledgement
Financial support from NCSR “Demokritos” and GSRT-Greece is greatly acknowledged.
Volume
2
Issue
11
Page
1259 - 1261
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Stergiopoulos T, Arabatzis I, Katsaros G, Falaras P. Binary Polyethylene Oxide/Titania Solid-State Redox Electrolyte for Highly Efficient Nanocrystalline TiO2 Photoelectrochemical Cells. Nano Letters. 2002;2(11):1259-1261. doi:10.1021/nl025798u
Stergiopoulos, T., Arabatzis, I., Katsaros, G., & Falaras, P. (2002). Binary Polyethylene Oxide/Titania Solid-State Redox Electrolyte for Highly Efficient Nanocrystalline TiO2 Photoelectrochemical Cells. Nano Letters, 2(11), 1259–1261. https://doi.org/10.1021/nl025798u
Stergiopoulos, Thomas, Iannis Arabatzis, Georgios Katsaros, and Polycarpos Falaras. “Binary Polyethylene Oxide/Titania Solid-State Redox Electrolyte for Highly Efficient Nanocrystalline TiO2 Photoelectrochemical Cells.” Nano Letters 2, no. 11 (2002): 1259–61. https://doi.org/10.1021/nl025798u.
T. Stergiopoulos, I. Arabatzis, G. Katsaros, and P. Falaras, “Binary Polyethylene Oxide/Titania Solid-State Redox Electrolyte for Highly Efficient Nanocrystalline TiO2 Photoelectrochemical Cells,” Nano Letters, vol. 2, no. 11, pp. 1259–1261, 2002.
Stergiopoulos T, Arabatzis I, Katsaros G, Falaras P. 2002. Binary Polyethylene Oxide/Titania Solid-State Redox Electrolyte for Highly Efficient Nanocrystalline TiO2 Photoelectrochemical Cells. Nano Letters. 2(11), 1259–1261.
Stergiopoulos, Thomas, et al. “Binary Polyethylene Oxide/Titania Solid-State Redox Electrolyte for Highly Efficient Nanocrystalline TiO2 Photoelectrochemical Cells.” Nano Letters, vol. 2, no. 11, American Chemical Society, 2002, pp. 1259–61, doi:10.1021/nl025798u.

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