[{"article_processing_charge":"No","author":[{"last_name":"Ibáñez","orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria","first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87"},{"last_name":"Zamani","full_name":"Zamani, Reza","first_name":"Reza"},{"first_name":"Wenhua","last_name":"Li","full_name":"Li, Wenhua"},{"first_name":"Alexey","full_name":"Shavel, Alexey","last_name":"Shavel"},{"first_name":"Jordi","last_name":"Arbiol","full_name":"Arbiol, Jordi"},{"last_name":"Morante","full_name":"Morante, Joan","first_name":"Joan"},{"first_name":"Andreu","last_name":"Cabot","full_name":"Cabot, Andreu"}],"publist_id":"7488","title":"Extending the nanocrystal synthesis control to quaternary compositions","date_updated":"2021-01-12T07:43:05Z","citation":{"mla":"Ibáñez, Maria, et al. “Extending the Nanocrystal Synthesis Control to Quaternary Compositions.” Crystal Growth and Design , vol. 12, no. 3, American Chemical Society (ACS), 2012, pp. 1085–90, doi:10.1021/cg201709c.","ama":"Ibáñez M, Zamani R, Li W, et al. Extending the nanocrystal synthesis control to quaternary compositions. Crystal Growth and Design . 2012;12(3):1085-1090. doi:10.1021/cg201709c","apa":"Ibáñez, M., Zamani, R., Li, W., Shavel, A., Arbiol, J., Morante, J., & Cabot, A. (2012). Extending the nanocrystal synthesis control to quaternary compositions. Crystal Growth and Design . American Chemical Society (ACS). https://doi.org/10.1021/cg201709c","short":"M. Ibáñez, R. Zamani, W. Li, A. Shavel, J. Arbiol, J. Morante, A. Cabot, Crystal Growth and Design 12 (2012) 1085–1090.","ieee":"M. Ibáñez et al., “Extending the nanocrystal synthesis control to quaternary compositions,” Crystal Growth and Design , vol. 12, no. 3. American Chemical Society (ACS), pp. 1085–1090, 2012.","chicago":"Ibáñez, Maria, Reza Zamani, Wenhua Li, Alexey Shavel, Jordi Arbiol, Joan Morante, and Andreu Cabot. “Extending the Nanocrystal Synthesis Control to Quaternary Compositions.” Crystal Growth and Design . American Chemical Society (ACS), 2012. https://doi.org/10.1021/cg201709c.","ista":"Ibáñez M, Zamani R, Li W, Shavel A, Arbiol J, Morante J, Cabot A. 2012. Extending the nanocrystal synthesis control to quaternary compositions. Crystal Growth and Design . 12(3), 1085–1090."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","extern":"1","type":"journal_article","article_type":"original","status":"public","_id":"338","page":"1085 - 1090","date_created":"2018-12-11T11:45:54Z","doi":"10.1021/cg201709c","date_published":"2012-01-01T00:00:00Z","issue":"3","volume":12,"publication_status":"published","year":"2012","publication":"Crystal Growth and Design ","language":[{"iso":"eng"}],"day":"01","publisher":"American Chemical Society (ACS)","quality_controlled":"1","intvolume":" 12","month":"01","abstract":[{"lang":"eng","text":"The ample chemical and structural freedom of quaternary compounds permits engineering materials that fulfill the requirements of a wide variety of applications. In this work, the mechanisms to achieve unprecedented size, shape, and composition control in quaternary nanocrystals are detailed. The described procedure allows obtaining tetrahedral and penta-tetrahedral quaternary nanocrystals with tuned size distributions and controlled compositions from a plethora of I 2-II-IV-VI 4 semiconductors."}],"acknowledgement":"This work was supported by the Spanish MICINN Projects MAT2008-05779, MAT2008-03400-E/MAT, MAT2010-15138, ENE2008-03277-E/CON, CSD2009-00050, and CSD2009-00013. M.I. thanks the Spanish MICINN for her Ph.D. grant. J.A. and R.Z. also acknowledge Generalitat de Catalunya 2009-SGR-770 and XaRMAE. A.C. is grateful for financial support through the Ramon y Cajal program of the Spanish MICINN.\r\n\r\n","oa_version":"None"},{"_id":"339","article_type":"original","type":"journal_article","status":"public","citation":{"mla":"Ibáñez, Maria, et al. “Composition Control and Thermoelectric Properties of Quaternary Chalcogenide Nanocrystals: The Case of Stannite Cu2CdSnSe4.” Chemistry of Materials, vol. 24, no. 3, American Chemical Society, 2012, pp. 562–70, doi:10.1021/cm2031812.","ama":"Ibáñez M, Cadavid D, Zamani R, et al. Composition control and thermoelectric properties of quaternary chalcogenide nanocrystals: The case of stannite Cu2CdSnSe4. Chemistry of Materials. 2012;24(3):562-570. doi:10.1021/cm2031812","apa":"Ibáñez, M., Cadavid, D., Zamani, R., García Castelló, N., Izquierdo Roca, V., Li, W., … Cabot, A. (2012). Composition control and thermoelectric properties of quaternary chalcogenide nanocrystals: The case of stannite Cu2CdSnSe4. Chemistry of Materials. American Chemical Society. https://doi.org/10.1021/cm2031812","short":"M. Ibáñez, D. Cadavid, R. Zamani, N. García Castelló, V. Izquierdo Roca, W. Li, A. Fairbrother, J. Prades, A. Shavel, J. Arbiol, A. Pérez Rodríguez, J. Morante, A. Cabot, Chemistry of Materials 24 (2012) 562–570.","ieee":"M. Ibáñez et al., “Composition control and thermoelectric properties of quaternary chalcogenide nanocrystals: The case of stannite Cu2CdSnSe4,” Chemistry of Materials, vol. 24, no. 3. American Chemical Society, pp. 562–570, 2012.","chicago":"Ibáñez, Maria, Doris Cadavid, Reza Zamani, Nuria García Castelló, Victora Izquierdo Roca, Wenhua Li, Andrew Fairbrother, et al. “Composition Control and Thermoelectric Properties of Quaternary Chalcogenide Nanocrystals: The Case of Stannite Cu2CdSnSe4.” Chemistry of Materials. American Chemical Society, 2012. https://doi.org/10.1021/cm2031812.","ista":"Ibáñez M, Cadavid D, Zamani R, García Castelló N, Izquierdo Roca V, Li W, Fairbrother A, Prades J, Shavel A, Arbiol J, Pérez Rodríguez A, Morante J, Cabot A. 2012. Composition control and thermoelectric properties of quaternary chalcogenide nanocrystals: The case of stannite Cu2CdSnSe4. Chemistry of Materials. 24(3), 562–570."},"date_updated":"2021-01-12T07:43:09Z","extern":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","first_name":"Maria","last_name":"Ibáñez","orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria"},{"first_name":"Doris","last_name":"Cadavid","full_name":"Cadavid, Doris"},{"full_name":"Zamani, Reza","last_name":"Zamani","first_name":"Reza"},{"first_name":"Nuria","last_name":"García Castelló","full_name":"García Castelló, Nuria"},{"first_name":"Victora","last_name":"Izquierdo Roca","full_name":"Izquierdo Roca, Victora"},{"first_name":"Wenhua","last_name":"Li","full_name":"Li, Wenhua"},{"full_name":"Fairbrother, Andrew","last_name":"Fairbrother","first_name":"Andrew"},{"first_name":"Joan","last_name":"Prades","full_name":"Prades, Joan"},{"full_name":"Shavel, Alexey","last_name":"Shavel","first_name":"Alexey"},{"last_name":"Arbiol","full_name":"Arbiol, Jordi","first_name":"Jordi"},{"first_name":"Alejandro","full_name":"Pérez Rodríguez, Alejandro","last_name":"Pérez Rodríguez"},{"last_name":"Morante","full_name":"Morante, Joan","first_name":"Joan"},{"last_name":"Cabot","full_name":"Cabot, Andreu","first_name":"Andreu"}],"publist_id":"7489","article_processing_charge":"No","title":"Composition control and thermoelectric properties of quaternary chalcogenide nanocrystals: The case of stannite Cu2CdSnSe4","abstract":[{"text":"A high-yield and upscalable colloidal synthesis route for the production of quaternary I 2-II-IV-VI 4 nanocrystals, particularly stannite Cu 2+xCd 1-xSnSe 4, with narrow size distribution and precisely controlled composition is presented. It is also shown here how the diversity of valences in the constituent elements allows an effective control of their electrical conductivity through the adjustment of the cation ratios. At the same time, while the crystallographic complexity of quaternary chalcogenides is associated with intrinsically low thermal conductivities, the reduction of the lattice dimensions to the nanoscale further reduces the materials thermal conductivity. In the specific case of the stannite crystal structure, a convenient slab distribution of the valence band maximum states permits a partial decoupling of the p-type electrical conductivity from both the Seebeck coefficient and the thermal conductivity. Combining these features, we demonstrate how an initial optimization of the nanocrystals Cd/Cu ratio allowed us to obtain low-temperature solution-processed materials with ZT values up to 0.71 at 685 K.","lang":"eng"}],"oa_version":"None","acknowledgement":"This work was supported by the Spanish MICINN Projects MAT2008-05779, MAT2008-03400-E/MAT, MAT2010-15138, ENE2008-03277-E/CON, CSD2009-00050. and CSD2009-00013. M.I. and N.G.-C. thank the Spanish MICINN for the PhD grant. J.A. and R.Z. also acknowledge Generalitat de Catalunya 2009-SGR-770 and XaRMAE. A.C. is thankful for financial support through the Ramon y Cajal program of the Spanish MICINN. N.G.-C. and J.D.P. are thankful for the computer resources, technical expertise and assistance provided by the Barcelona Supercomputing Center - Centro Nacional de Supercomputación.","publisher":"American Chemical Society","quality_controlled":"1","month":"01","intvolume":" 24","publication_status":"published","year":"2012","day":"31","publication":"Chemistry of Materials","language":[{"iso":"eng"}],"page":"562 - 570","doi":"10.1021/cm2031812","volume":24,"date_published":"2012-01-31T00:00:00Z","issue":"3","date_created":"2018-12-11T11:45:54Z"},{"citation":{"ista":"Shavel A, Cadavid D, Ibáñez M, Carrete A, Cabot A. 2012. Continuous production of Cu inf 2 inf ZnSnS inf 4 inf nanocrystals in a flow reactor. Journal of the American Chemical Society. 134(3), 1438–1441.","chicago":"Shavel, Alexey, Doris Cadavid, Maria Ibáñez, Alex Carrete, and Andreu Cabot. “Continuous Production of Cu Inf 2 Inf ZnSnS Inf 4 Inf Nanocrystals in a Flow Reactor.” Journal of the American Chemical Society. ACS, 2012. https://doi.org/10.1021/ja209688a.","short":"A. Shavel, D. Cadavid, M. Ibáñez, A. Carrete, A. Cabot, Journal of the American Chemical Society 134 (2012) 1438–1441.","ieee":"A. Shavel, D. Cadavid, M. Ibáñez, A. Carrete, and A. Cabot, “Continuous production of Cu inf 2 inf ZnSnS inf 4 inf nanocrystals in a flow reactor,” Journal of the American Chemical Society, vol. 134, no. 3. ACS, pp. 1438–1441, 2012.","ama":"Shavel A, Cadavid D, Ibáñez M, Carrete A, Cabot A. Continuous production of Cu inf 2 inf ZnSnS inf 4 inf nanocrystals in a flow reactor. Journal of the American Chemical Society. 2012;134(3):1438-1441. doi:10.1021/ja209688a","apa":"Shavel, A., Cadavid, D., Ibáñez, M., Carrete, A., & Cabot, A. (2012). Continuous production of Cu inf 2 inf ZnSnS inf 4 inf nanocrystals in a flow reactor. Journal of the American Chemical Society. ACS. https://doi.org/10.1021/ja209688a","mla":"Shavel, Alexey, et al. “Continuous Production of Cu Inf 2 Inf ZnSnS Inf 4 Inf Nanocrystals in a Flow Reactor.” Journal of the American Chemical Society, vol. 134, no. 3, ACS, 2012, pp. 1438–41, doi:10.1021/ja209688a."},"date_updated":"2021-01-12T07:43:13Z","extern":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"last_name":"Shavel","full_name":"Shavel, Alexey","first_name":"Alexey"},{"first_name":"Doris","full_name":"Cadavid, Doris","last_name":"Cadavid"},{"first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria","last_name":"Ibáñez"},{"first_name":"Alex","last_name":"Carrete","full_name":"Carrete, Alex"},{"first_name":"Andreu","last_name":"Cabot","full_name":"Cabot, Andreu"}],"publist_id":"7490","article_processing_charge":"No","title":"Continuous production of Cu inf 2 inf ZnSnS inf 4 inf nanocrystals in a flow reactor","_id":"340","type":"journal_article","article_type":"original","status":"public","publication_status":"published","year":"2012","day":"02","publication":"Journal of the American Chemical Society","language":[{"iso":"eng"}],"page":"1438 - 1441","date_published":"2012-01-02T00:00:00Z","issue":"3","volume":134,"doi":"10.1021/ja209688a","date_created":"2018-12-11T11:45:54Z","abstract":[{"lang":"eng","text":"A procedure for the continuous production of Cu 2ZnSnS 4 (CZTS) nanoparticles with controlled composition is presented. CZTS nanoparticles were prepared through the reaction of the metals' amino complexes with elemental sulfur in a continuous-flow reactor at moderate temperatures (300-330 °C). High-resolution transmission electron microscopy and X-ray diffraction analysis showed the nanocrystals to have a crystallographic structure compatible with that of the kesterite. Chemical characterization of the materials showed the presence of the four elements in each individual nanocrystal. Composition control was achieved by adjusting the solution flow rate through the reactor and the proper choice of the nominal precursor concentration within the flowing solution. Single-particle analysis revealed a composition distribution within each sample, which was optimized at the highest synthesis temperatures used. "}],"oa_version":"None","acknowledgement":"This work was supported by the Spanish MICINN Projects MAT2008-05779, MAT2008-03400-E/MAT, CDS2009-00050, CSD2009-00013, and ENE2008-03277-E/CON. M.I. thanks the Spanish MICINN for her Ph.D. grant. A.C. is thankful for financial support through the Ramón y Cajal Program.","quality_controlled":"1","publisher":"ACS","month":"01","intvolume":" 134"},{"acknowledgement":"Acknowledgments The research was supported by the European Regional Development Funds and the Spanish MICINN Projects MAT2008-05779, MAT2008-03400-E/MAT, MAT2010-15138, MAT2010-21510, CSD2009-00050, and ENE2008-03277-E/CON. M.I. is grateful to the Spanish MIC-INN for her PhD grant. A. Cirera acknowledges support from ICREA Academia program. A. Cabot is grateful to the Spanish MICINN for financial support through the Ramón y Cajal program.","oa_version":"None","abstract":[{"lang":"eng","text":"Nanocomposites are highly promising materials to enhance the efficiency of current thermoelectric devices. A straightforward and at the same time highly versatile and controllable approach to produce nanocomposites is the assembly of solution-processed nanocrystal building blocks. The convenience of this bottom-up approach to produce nanocomposites with homogeneous phase distributions and adjustable composition is demonstrated here by blending Ag2Te and PbTe colloidal nanocrystals to form Ag2Te–PbTe bulk nanocomposites. The thermoelectric properties of these nanocomposites are analyzed in the temperature range from 300 to 700 K. The evolution of their electrical conductivity and Seebeck coefficient is discussed in terms of the blend composition and the characteristics of the constituent materials. "}],"intvolume":" 14","month":"12","publisher":"Kluwer","quality_controlled":"1","language":[{"iso":"eng"}],"publication":"Journal of Nanoparticle Research","day":"01","year":"2012","publication_status":"published","date_created":"2018-12-11T11:45:56Z","issue":"12","date_published":"2012-12-01T00:00:00Z","volume":14,"doi":"10.1007/s11051-012-1328-0","_id":"345","status":"public","type":"journal_article","article_type":"original","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","extern":"1","citation":{"chicago":"Cadavid, Doris, Maria Ibáñez, Stéphane Gorsse, Antonio López, Albert Cirera, Joan Morante, and Andreu Cabot. “Bottom-up Processing of Thermoelectric Nanocomposites from Colloidal Nanocrystal Building Blocks: The Case of Ag2Te–PbTe.” Journal of Nanoparticle Research. Kluwer, 2012. https://doi.org/10.1007/s11051-012-1328-0.","ista":"Cadavid D, Ibáñez M, Gorsse S, López A, Cirera A, Morante J, Cabot A. 2012. Bottom-up processing of thermoelectric nanocomposites from colloidal nanocrystal building blocks: The case of Ag2Te–PbTe. Journal of Nanoparticle Research. 14(12).","mla":"Cadavid, Doris, et al. “Bottom-up Processing of Thermoelectric Nanocomposites from Colloidal Nanocrystal Building Blocks: The Case of Ag2Te–PbTe.” Journal of Nanoparticle Research, vol. 14, no. 12, Kluwer, 2012, doi:10.1007/s11051-012-1328-0.","apa":"Cadavid, D., Ibáñez, M., Gorsse, S., López, A., Cirera, A., Morante, J., & Cabot, A. (2012). Bottom-up processing of thermoelectric nanocomposites from colloidal nanocrystal building blocks: The case of Ag2Te–PbTe. Journal of Nanoparticle Research. Kluwer. https://doi.org/10.1007/s11051-012-1328-0","ama":"Cadavid D, Ibáñez M, Gorsse S, et al. Bottom-up processing of thermoelectric nanocomposites from colloidal nanocrystal building blocks: The case of Ag2Te–PbTe. Journal of Nanoparticle Research. 2012;14(12). doi:10.1007/s11051-012-1328-0","short":"D. Cadavid, M. Ibáñez, S. Gorsse, A. López, A. Cirera, J. Morante, A. Cabot, Journal of Nanoparticle Research 14 (2012).","ieee":"D. Cadavid et al., “Bottom-up processing of thermoelectric nanocomposites from colloidal nanocrystal building blocks: The case of Ag2Te–PbTe,” Journal of Nanoparticle Research, vol. 14, no. 12. Kluwer, 2012."},"date_updated":"2021-01-12T07:43:32Z","title":"Bottom-up processing of thermoelectric nanocomposites from colloidal nanocrystal building blocks: The case of Ag2Te–PbTe","article_processing_charge":"No","author":[{"full_name":"Cadavid, Doris","last_name":"Cadavid","first_name":"Doris"},{"last_name":"Ibáñez","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87"},{"first_name":"Stéphane","last_name":"Gorsse","full_name":"Gorsse, Stéphane"},{"first_name":"Antonio","full_name":"López, Antonio","last_name":"López"},{"first_name":"Albert","full_name":"Cirera, Albert","last_name":"Cirera"},{"first_name":"Joan","last_name":"Morante","full_name":"Morante, Joan"},{"first_name":"Andreu","full_name":"Cabot, Andreu","last_name":"Cabot"}],"publist_id":"7485"},{"title":"Cu 2ZnGeSe 4 nanocrystals: Synthesis and thermoelectric properties","publist_id":"7487","author":[{"orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria","last_name":"Ibáñez","id":"43C61214-F248-11E8-B48F-1D18A9856A87","first_name":"Maria"},{"full_name":"Zamani, Reza","last_name":"Zamani","first_name":"Reza"},{"last_name":"Lalonde","full_name":"Lalonde, Aaron","first_name":"Aaron"},{"first_name":"Doris","last_name":"Cadavid","full_name":"Cadavid, Doris"},{"last_name":"Li","full_name":"Li, Wenhua","first_name":"Wenhua"},{"last_name":"Shavel","full_name":"Shavel, Alexey","first_name":"Alexey"},{"first_name":"Jordi","last_name":"Arbiol","full_name":"Arbiol, Jordi"},{"last_name":"Morante","full_name":"Morante, Joan","first_name":"Joan"},{"first_name":"Stéphane","full_name":"Gorsse, Stéphane","last_name":"Gorsse"},{"first_name":"G Jeffrey","full_name":"Snyder, G Jeffrey","last_name":"Snyder"},{"first_name":"Andreu","last_name":"Cabot","full_name":"Cabot, Andreu"}],"article_processing_charge":"No","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","citation":{"ista":"Ibáñez M, Zamani R, Lalonde A, Cadavid D, Li W, Shavel A, Arbiol J, Morante J, Gorsse S, Snyder GJ, Cabot A. 2012. Cu 2ZnGeSe 4 nanocrystals: Synthesis and thermoelectric properties. Journal of the American Chemical Society. 134(9), 4060–4063.","chicago":"Ibáñez, Maria, Reza Zamani, Aaron Lalonde, Doris Cadavid, Wenhua Li, Alexey Shavel, Jordi Arbiol, et al. “Cu 2ZnGeSe 4 Nanocrystals: Synthesis and Thermoelectric Properties.” Journal of the American Chemical Society. ACS, 2012. https://doi.org/10.1021/ja211952z.","short":"M. Ibáñez, R. Zamani, A. Lalonde, D. Cadavid, W. Li, A. Shavel, J. Arbiol, J. Morante, S. Gorsse, G.J. Snyder, A. Cabot, Journal of the American Chemical Society 134 (2012) 4060–4063.","ieee":"M. Ibáñez et al., “Cu 2ZnGeSe 4 nanocrystals: Synthesis and thermoelectric properties,” Journal of the American Chemical Society, vol. 134, no. 9. ACS, pp. 4060–4063, 2012.","apa":"Ibáñez, M., Zamani, R., Lalonde, A., Cadavid, D., Li, W., Shavel, A., … Cabot, A. (2012). Cu 2ZnGeSe 4 nanocrystals: Synthesis and thermoelectric properties. Journal of the American Chemical Society. ACS. https://doi.org/10.1021/ja211952z","ama":"Ibáñez M, Zamani R, Lalonde A, et al. Cu 2ZnGeSe 4 nanocrystals: Synthesis and thermoelectric properties. Journal of the American Chemical Society. 2012;134(9):4060-4063. doi:10.1021/ja211952z","mla":"Ibáñez, Maria, et al. “Cu 2ZnGeSe 4 Nanocrystals: Synthesis and Thermoelectric Properties.” Journal of the American Chemical Society, vol. 134, no. 9, ACS, 2012, pp. 4060–63, doi:10.1021/ja211952z."},"quality_controlled":"1","publisher":"ACS","oa":1,"acknowledgement":"This work was supported by the Spanish MICINN Projects MAT2008-05779, MAT2008-03400-E/MAT, MAT2010-15138, ENE2008-03277-E/CON, CSD2009-00050, and CSD2009-00013. M.I. thanks the Spanish MICINN for her Ph.D. Grant. J.A. and R.Z. also acknowledge Generalitat de Catalunya 2009-SGR-770 and XaRMAE. A.C. is thankful for financial support through the Ramon y Cajal Program of the Spanish MICINN.","date_published":"2012-03-07T00:00:00Z","doi":"10.1021/ja211952z","date_created":"2018-12-11T11:45:57Z","page":"4060 - 4063","day":"07","publication":"Journal of the American Chemical Society","year":"2012","status":"public","article_type":"original","type":"journal_article","_id":"347","extern":"1","date_updated":"2021-01-12T07:43:40Z","month":"03","intvolume":" 134","main_file_link":[{"url":"https://authors.library.caltech.edu/30261/","open_access":"1"}],"oa_version":"None","abstract":[{"lang":"eng","text":"A synthetic route for producing Cu 2ZnGeSe 4 nanocrystals with narrow size distributions and controlled composition is presented. These nanocrystals were used to produce densely packed nanomaterials by hot-pressing. From the characterization of the thermoelectric properties of these nanomaterials, Cu 2ZnGeSe 4 is demonstrated to show excellent thermoelectric properties. A very preliminary adjustment of the nanocrystal composition has already resulted in a figure of merit of up to 0.55 at 450°C. "}],"issue":"9","volume":134,"language":[{"iso":"eng"}],"publication_status":"published"}]