@article{14663, abstract = {As a bottleneck in the direct synthesis of hydrogen peroxide, the development of an efficient palladium-based catalyst has garnered great attention. However, elusive active centers and reaction mechanism issues inhibit further optimization of its performance. In this work, advanced microkinetic modeling with the adsorbate–adsorbate interaction and nanoparticle size effect based on first-principles calculations is developed. A full mechanism uncovering the significance of adsorbate–adsorbate interaction is determined on Pd nanoparticles. We demonstrate unambiguously that Pd(100) with main coverage species of O2 and H is beneficial to H2O2 production, being consistent with experimental operando observation, while H2O forms on Pd(111) covered by O species and Pd(211) covered by O and OH species. Kinetic analyses further enable quantitative estimation of the influence of temperature, pressure, and particle size. Large-size Pd nanoparticles are found to achieve a high H2O2 reaction rate when the operating conditions are moderate temperature and higher oxygen partial pressure. We reveal that specific facets of the Pd nanoparticles are crucial factors for their selectivity and activity. Consistent with the experiment, the production of H2O2 is discovered to be more favorable on Pd nanoparticles containing Pd(100) facets. The ratio of H2/O2 induces substantial variations in the coverage of intermediates of O2 and H on Pd(100), resulting in a change in product selectivity.}, author = {Zhao, Jinyan and Yao, Zihao and Bunting, Rhys and Hu, P. and Wang, Jianguo}, issn = {2155-5435}, journal = {ACS Catalysis}, number = {22}, pages = {15054--15073}, publisher = {American Chemical Society}, title = {{Microkinetic modeling with size-dependent and adsorbate-adsorbate interactions for the direct synthesis of H₂O₂ over Pd nanoparticles}}, doi = {10.1021/acscatal.3c03893}, volume = {13}, year = {2023}, } @article{14667, abstract = {For large dimensional non-Hermitian random matrices X with real or complex independent, identically distributed, centered entries, we consider the fluctuations of f (X) as a matrix where f is an analytic function around the spectrum of X. We prove that for a generic bounded square matrix A, the quantity Tr f (X)A exhibits Gaussian fluctuations as the matrix size grows to infinity, which consists of two independent modes corresponding to the tracial and traceless parts of A. We find a new formula for the variance of the traceless part that involves the Frobenius norm of A and the L2-norm of f on the boundary of the limiting spectrum. }, author = {Erdös, László and Ji, Hong Chang}, issn = {0246-0203}, journal = {Annales de l'institut Henri Poincare (B) Probability and Statistics}, number = {4}, pages = {2083--2105}, publisher = {Institute of Mathematical Statistics}, title = {{Functional CLT for non-Hermitian random matrices}}, doi = {10.1214/22-AIHP1304}, volume = {59}, year = {2023}, } @article{14662, abstract = {We consider a class of polaron models, including the Fröhlich model, at zero total momentum, and show that at sufficiently weak coupling there are no excited eigenvalues below the essential spectrum.}, author = {Seiringer, Robert}, issn = {1664-0403}, journal = {Journal of Spectral Theory}, number = {3}, pages = {1045--1055}, publisher = {EMS Press}, title = {{Absence of excited eigenvalues for Fröhlich type polaron models at weak coupling}}, doi = {10.4171/JST/469}, volume = {13}, year = {2023}, } @article{14652, abstract = {In order to demonstrate the stability of newly proposed iridium-based Ir2Cr(In,Sn) and IrRhCr(In,Sn) heusler alloys, we present ab-initio analysis of these alloys by examining various properties to prove their stability. The stability of these alloys can be inferred from different cohesive and formation energies as well as positive phonon frequencies. Their electronic structure results indicate that they are semi-metals in nature. The magnetic moments are computed using the Slater-Pauling formula and exhibit a high value, with the Cr atom contributing the most in all alloys. Mulliken’s charge analysis results show that our alloys contain a range of linkages, mainly ionic and covalent ones. The ductility and mechanical stability of these alloys are confirmed by elastic constants viz. Poisson’s ratio, Pugh’s ratio, and many different types of elastic moduli.}, author = {Gupta, Shyam Lal and Singh, Saurabh and Kumar, Sumit and Anupam, Unknown and Thakur, Samjeet Singh and Kumar, Ashish and Panwar, Sanjay and Diwaker, D.}, issn = {0921-4526}, journal = {Physica B: Condensed Matter}, publisher = {Elsevier}, title = {{Ab-initio stability of Iridium based newly proposed full and quaternary heusler alloys}}, doi = {10.1016/j.physb.2023.415539}, volume = {674}, year = {2023}, } @article{12487, abstract = {Sleep plays a key role in preserving brain function, keeping the brain network in a state that ensures optimal computational capabilities. Empirical evidence indicates that such a state is consistent with criticality, where scale-free neuronal avalanches emerge. However, the relationship between sleep, emergent avalanches, and criticality remains poorly understood. Here we fully characterize the critical behavior of avalanches during sleep, and study their relationship with the sleep macro- and micro-architecture, in particular the cyclic alternating pattern (CAP). We show that avalanche size and duration distributions exhibit robust power laws with exponents approximately equal to −3/2 e −2, respectively. Importantly, we find that sizes scale as a power law of the durations, and that all critical exponents for neuronal avalanches obey robust scaling relations, which are consistent with the mean-field directed percolation universality class. Our analysis demonstrates that avalanche dynamics depends on the position within the NREM-REM cycles, with the avalanche density increasing in the descending phases and decreasing in the ascending phases of sleep cycles. Moreover, we show that, within NREM sleep, avalanche occurrence correlates with CAP activation phases, particularly A1, which are the expression of slow wave sleep propensity and have been proposed to be beneficial for cognitive processes. The results suggest that neuronal avalanches, and thus tuning to criticality, actively contribute to sleep development and play a role in preserving network function. Such findings, alongside characterization of the universality class for avalanches, open new avenues to the investigation of functional role of criticality during sleep with potential clinical application.Significance statementWe fully characterize the critical behavior of neuronal avalanches during sleep, and show that avalanches follow precise scaling laws that are consistent with the mean-field directed percolation universality class. The analysis provides first evidence of a functional relationship between avalanche occurrence, slow-wave sleep dynamics, sleep stage transitions and occurrence of CAP phase A during NREM sleep. Because CAP is considered one of the major guardians of NREM sleep that allows the brain to dynamically react to external perturbation and contributes to the cognitive consolidation processes occurring in sleep, our observations suggest that neuronal avalanches at criticality are associated with flexible response to external inputs and to cognitive processes, a key assumption of the critical brain hypothesis.}, author = {Scarpetta, Silvia and Morrisi, Niccolò and Mutti, Carlotta and Azzi, Nicoletta and Trippi, Irene and Ciliento, Rosario and Apicella, Ilenia and Messuti, Giovanni and Angiolelli, Marianna and Lombardi, Fabrizio and Parrino, Liborio and Vaudano, Anna Elisabetta}, issn = {2589-0042}, journal = {iScience}, number = {10}, pages = {107840}, publisher = {Elsevier}, title = {{Criticality of neuronal avalanches in human sleep and their relationship with sleep macro- and micro-architecture}}, doi = {10.1016/j.isci.2023.107840}, volume = {26}, year = {2023}, } @article{12696, abstract = {Background: Fighting disease while fighting rivals exposes males to constraints and tradeoffs during male-male competition. We here tested how both the stage and intensity of infection with the fungal pathogen Metarhizium robertsii interfered with fighting success in Cardiocondyla obscurior ant males. Males of this species have evolved long lifespans during which they can gain many matings with the young queens of the colony, if successful in male-male competition. Since male fights occur inside the colony, the outcome of male-male competition can further be biased by interference of the colony’s worker force. Results: We found that severe, but not yet mild, infection strongly impaired male fighting success. In late-stage infection, this could be attributed to worker aggression directed towards the infected rather than the healthy male and an already very high male morbidity even in the absence of fighting. Shortly after pathogen exposure, however, male mortality was particularly increased during combat. Since these males mounted a strong immune response, their reduced fighting success suggests a trade-off between immune investment and competitive ability already early in the infection. Even if the males themselves showed no difference in the number of attacks they raised against their healthy rivals across infection stages and levels, severely infected males were thus losing in male-male competition from an early stage of infection on. Conclusions: Males of the ant C. obscurior have evolved high immune investment, triggering an effective immune response very fast after fungal exposure. This allows them to cope with mild pathogen exposures without cost to their success in male-male competition, and hence to gain multiple mating opportunities with the emerging virgin queens of the colony. Under severe infection, however, they are weak fighters and rarely survive a combat already at early infection when raising an immune response, as well as at progressed infection, when they are morbid and preferentially targeted by worker aggression. Workers thereby remove males that pose a future disease threat by biasing male-male competition. Our study thus revealed a novel social immunity mechanism how social insect workers protect the colony against disease risk.}, author = {Metzler, Sina and Kirchner, Jessica and Grasse, Anna V and Cremer, Sylvia}, issn = {2730-7182}, journal = {BMC Ecology and Evolution}, publisher = {Springer Nature}, title = {{Trade-offs between immunity and competitive ability in fighting ant males}}, doi = {10.1186/s12862-023-02137-7}, volume = {23}, year = {2023}, } @article{14659, abstract = {Understanding the response of Himalayan glaciers to global warming is vital because of their role as a water source for the Asian subcontinent. However, great uncertainties still exist on the climate drivers of past and present glacier changes across scales. Here, we analyse continuous hourly climate station data from a glacierized elevation (Pyramid station, Mount Everest) since 1994 together with other ground observations and climate reanalysis. We show that a decrease in maximum air temperature and precipitation occurred during the last three decades at Pyramid in response to global warming. Reanalysis data suggest a broader occurrence of this effect in the glacierized areas of the Himalaya. We hypothesize that the counterintuitive cooling is caused by enhanced sensible heat exchange and the associated increase in glacier katabatic wind, which draws cool air downward from higher elevations. The stronger katabatic winds have also lowered the elevation of local wind convergence, thereby diminishing precipitation in glacial areas and negatively affecting glacier mass balance. This local cooling may have partially preserved glaciers from melting and could help protect the periglacial environment.}, author = {Salerno, Franco and Guyennon, Nicolas and Yang, Kun and Shaw, Thomas and Lin, Changgui and Colombo, Nicola and Romano, Emanuele and Gruber, Stephan and Bolch, Tobias and Alessandri, Andrea and Cristofanelli, Paolo and Putero, Davide and Diolaiuti, Guglielmina and Tartari, Gianni and Verza, Gianpietro and Thakuri, Sudeep and Balsamo, Gianpaolo and Miles, Evan S. and Pellicciotti, Francesca}, issn = {1752-0908}, journal = {Nature Geoscience}, pages = {1120--1127}, publisher = {Springer Nature}, title = {{Local cooling and drying induced by Himalayan glaciers under global warming}}, doi = {10.1038/s41561-023-01331-y}, volume = {16}, year = {2023}, } @article{12786, abstract = {AMPA glutamate receptors (AMPARs) mediate excitatory neurotransmission throughout the brain. Their signalling is uniquely diversified by brain region-specific auxiliary subunits, providing an opportunity for the development of selective therapeutics. AMPARs associated with TARP γ8 are enriched in the hippocampus, and are targets of emerging anti-epileptic drugs. To understand their therapeutic activity, we determined cryo-EM structures of the GluA1/2-γ8 receptor associated with three potent, chemically diverse ligands. We find that despite sharing a lipid-exposed and water-accessible binding pocket, drug action is differentially affected by binding-site mutants. Together with patch-clamp recordings and MD simulations we also demonstrate that ligand-triggered reorganisation of the AMPAR-TARP interface contributes to modulation. Unexpectedly, one ligand (JNJ-61432059) acts bifunctionally, negatively affecting GluA1 but exerting positive modulatory action on GluA2-containing AMPARs, in a TARP stoichiometry-dependent manner. These results further illuminate the action of TARPs, demonstrate the sensitive balance between positive and negative modulatory action, and provide a mechanistic platform for development of both positive and negative selective AMPAR modulators.}, author = {Zhang, Danyang and Lape, Remigijus and Shaikh, Saher A. and Kohegyi, Bianka K. and Watson, Jake and Cais, Ondrej and Nakagawa, Terunaga and Greger, Ingo H.}, issn = {2041-1723}, journal = {Nature Communications}, publisher = {Springer Nature}, title = {{Modulatory mechanisms of TARP γ8-selective AMPA receptor therapeutics}}, doi = {10.1038/s41467-023-37259-5}, volume = {14}, year = {2023}, } @misc{12693, abstract = {See Readme File for further information.}, author = {Cremer, Sylvia}, publisher = {Institute of Science and Technology Austria}, title = {{Source data for Metzler et al, 2023: Trade-offs between immunity and competitive ability in fighting ant males }}, doi = {10.15479/AT:ISTA:12693}, year = {2023}, } @article{13168, abstract = {Urban-living individuals are exposed to many environmental factors that may combine and interact to influence mental health. While individual factors of an urban environment have been investigated in isolation, no attempt has been made to model how complex, real-life exposure to living in the city relates to brain and mental health, and how this is moderated by genetic factors. Using the data of 156,075 participants from the UK Biobank, we carried out sparse canonical correlation analyses to investigate the relationships between urban environments and psychiatric symptoms. We found an environmental profile of social deprivation, air pollution, street network and urban land-use density that was positively correlated with an affective symptom group (r = 0.22, Pperm < 0.001), mediated by brain volume differences consistent with reward processing, and moderated by genes enriched for stress response, including CRHR1, explaining 2.01% of the variance in brain volume differences. Protective factors such as greenness and generous destination accessibility were negatively correlated with an anxiety symptom group (r = 0.10, Pperm < 0.001), mediated by brain regions necessary for emotion regulation and moderated by EXD3, explaining 1.65% of the variance. The third urban environmental profile was correlated with an emotional instability symptom group (r = 0.03, Pperm < 0.001). Our findings suggest that different environmental profiles of urban living may influence specific psychiatric symptom groups through distinct neurobiological pathways.}, author = {Xu, Jiayuan and Liu, Nana and Polemiti, Elli and Garcia-Mondragon, Liliana and Tang, Jie and Liu, Xiaoxuan and Lett, Tristram and Yu, Le and Nöthen, Markus M. and Feng, Jianfeng and Yu, Chunshui and Marquand, Andre and Schumann, Gunter and Walter, Henrik and Heinz, Andreas and Ralser, Markus and Twardziok, Sven and Vaidya, Nilakshi and Serin, Emin and Jentsch, Marcel and Hitchen, Esther and Eils, Roland and Taron, Ulrike Helene and Schütz, Tatjana and Schepanski, Kerstin and Banks, Jamie and Banaschewski, Tobias and Jansone, Karina and Christmann, Nina and Meyer-Lindenberg, Andreas and Tost, Heike and Holz, Nathalie and Schwarz, Emanuel and Stringaris, Argyris and Neidhart, Maja and Nees, Frauke and Siehl, Sebastian and A. Andreassen, Ole and T. Westlye, Lars and Van Der Meer, Dennis and Fernandez, Sara and Kjelkenes, Rikka and Ask, Helga and Rapp, Michael and Tschorn, Mira and Böttger, Sarah Jane and Novarino, Gaia and Marr, Lena and Slater, Mel and Viapiana, Guillem Feixas and Orosa, Francisco Eiroa and Gallego, Jaime and Pastor, Alvaro and Forstner, Andreas and Hoffmann, Per and M. Nöthen, Markus and J. Forstner, Andreas and Claus, Isabelle and Miller, Abbi and Heilmann-Heimbach, Stefanie and Sommer, Peter and Boye, Mona and Wilbertz, Johannes and Schmitt, Karen and Jirsa, Viktor and Petkoski, Spase and Pitel, Séverine and Otten, Lisa and Athanasiadis, Anastasios Polykarpos and Pearmund, Charlie and Spanlang, Bernhard and Alvarez, Elena and Sanchez, Mavi and Giner, Arantxa and Hese, Sören and Renner, Paul and Jia, Tianye and Gong, Yanting and Xia, Yunman and Chang, Xiao and Calhoun, Vince and Liu, Jingyu and Thompson, Paul and Clinton, Nicholas and Desrivieres, Sylvane and H. Young, Allan and Stahl, Bernd and Ogoh, George}, issn = {1546-170X}, journal = {Nature Medicine}, pages = {1456--1467}, publisher = {Springer Nature}, title = {{Effects of urban living environments on mental health in adults}}, doi = {10.1038/s41591-023-02365-w}, volume = {29}, year = {2023}, } @inproceedings{12976, abstract = {3D printing based on continuous deposition of materials, such as filament-based 3D printing, has seen widespread adoption thanks to its versatility in working with a wide range of materials. An important shortcoming of this type of technology is its limited multi-material capabilities. While there are simple hardware designs that enable multi-material printing in principle, the required software is heavily underdeveloped. A typical hardware design fuses together individual materials fed into a single chamber from multiple inlets before they are deposited. This design, however, introduces a time delay between the intended material mixture and its actual deposition. In this work, inspired by diverse path planning research in robotics, we show that this mechanical challenge can be addressed via improved printer control. We propose to formulate the search for optimal multi-material printing policies in a reinforcement learning setup. We put forward a simple numerical deposition model that takes into account the non-linear material mixing and delayed material deposition. To validate our system we focus on color fabrication, a problem known for its strict requirements for varying material mixtures at a high spatial frequency. We demonstrate that our learned control policy outperforms state-of-the-art hand-crafted algorithms.}, author = {Liao, Kang and Tricard, Thibault and Piovarci, Michael and Seidel, Hans-Peter and Babaei, Vahid}, booktitle = {2023 IEEE International Conference on Robotics and Automation}, issn = {1050-4729}, keywords = {reinforcement learning, deposition, control, color, multi-filament}, location = {London, United Kingdom}, pages = {12345--12352}, publisher = {IEEE}, title = {{Learning deposition policies for fused multi-material 3D printing}}, doi = {10.1109/ICRA48891.2023.10160465}, volume = {2023}, year = {2023}, } @article{13164, abstract = {Molecular compatibility between gametes is a prerequisite for successful fertilization. As long as a sperm and egg can recognize and bind each other via their surface proteins, gamete fusion may occur even between members of separate species, resulting in hybrids that can impact speciation. The egg membrane protein Bouncer confers species specificity to gamete interactions between medaka and zebrafish, preventing their cross-fertilization. Here, we leverage this specificity to uncover distinct amino acid residues and N-glycosylation patterns that differentially influence the function of medaka and zebrafish Bouncer and contribute to cross-species incompatibility. Curiously, in contrast to the specificity observed for medaka and zebrafish Bouncer, seahorse and fugu Bouncer are compatible with both zebrafish and medaka sperm, in line with the pervasive purifying selection that dominates Bouncer’s evolution. The Bouncer-sperm interaction is therefore the product of seemingly opposing evolutionary forces that, for some species, restrict fertilization to closely related fish, and for others, allow broad gamete compatibility that enables hybridization.}, author = {Gert, Krista R.B. and Panser, Karin and Surm, Joachim and Steinmetz, Benjamin S. and Schleiffer, Alexander and Jovine, Luca and Moran, Yehu and Kondrashov, Fyodor and Pauli, Andrea}, issn = {2041-1723}, journal = {Nature Communications}, publisher = {Springer Nature}, title = {{Divergent molecular signatures in fish Bouncer proteins define cross-fertilization boundaries}}, doi = {10.1038/s41467-023-39317-4}, volume = {14}, year = {2023}, } @article{12313, abstract = {Let P be a nontorsion point on an elliptic curve defined over a number field K and consider the sequence {Bn}n∈N of the denominators of x(nP). We prove that every term of the sequence of the Bn has a primitive divisor for n greater than an effectively computable constant that we will explicitly compute. This constant will depend only on the model defining the curve.}, author = {Verzobio, Matteo}, issn = {0030-8730}, journal = {Pacific Journal of Mathematics}, number = {2}, pages = {331--351}, publisher = {Mathematical Sciences Publishers}, title = {{Some effectivity results for primitive divisors of elliptic divisibility sequences}}, doi = {10.2140/pjm.2023.325.331}, volume = {325}, year = {2023}, } @article{13145, abstract = {We prove a characterization of the Dirichlet–Ferguson measure over an arbitrary finite diffuse measure space. We provide an interpretation of this characterization in analogy with the Mecke identity for Poisson point processes.}, author = {Dello Schiavo, Lorenzo and Lytvynov, Eugene}, issn = {1083-589X}, journal = {Electronic Communications in Probability}, pages = {1--12}, publisher = {Institute of Mathematical Statistics}, title = {{A Mecke-type characterization of the Dirichlet–Ferguson measure}}, doi = {10.1214/23-ECP528}, volume = {28}, year = {2023}, } @article{12838, abstract = {We study the problem of high-dimensional multiple packing in Euclidean space. Multiple packing is a natural generalization of sphere packing and is defined as follows. Let N > 0 and L ∈ Z ≽2 . A multiple packing is a set C of points in R n such that any point in R n lies in the intersection of at most L – 1 balls of radius √ nN around points in C . Given a well-known connection with coding theory, multiple packings can be viewed as the Euclidean analog of list-decodable codes, which are well-studied for finite fields. In this paper, we derive the best known lower bounds on the optimal density of list-decodable infinite constellations for constant L under a stronger notion called average-radius multiple packing. To this end, we apply tools from high-dimensional geometry and large deviation theory.}, author = {Zhang, Yihan and Vatedka, Shashank}, issn = {1557-9654}, journal = {IEEE Transactions on Information Theory}, number = {7}, pages = {4513--4527}, publisher = {IEEE}, title = {{Multiple packing: Lower bounds via infinite constellations}}, doi = {10.1109/TIT.2023.3260950}, volume = {69}, year = {2023}, } @inproceedings{13228, abstract = {A machine-learned system that is fair in static decision-making tasks may have biased societal impacts in the long-run. This may happen when the system interacts with humans and feedback patterns emerge, reinforcing old biases in the system and creating new biases. While existing works try to identify and mitigate long-run biases through smart system design, we introduce techniques for monitoring fairness in real time. Our goal is to build and deploy a monitor that will continuously observe a long sequence of events generated by the system in the wild, and will output, with each event, a verdict on how fair the system is at the current point in time. The advantages of monitoring are two-fold. Firstly, fairness is evaluated at run-time, which is important because unfair behaviors may not be eliminated a priori, at design-time, due to partial knowledge about the system and the environment, as well as uncertainties and dynamic changes in the system and the environment, such as the unpredictability of human behavior. Secondly, monitors are by design oblivious to how the monitored system is constructed, which makes them suitable to be used as trusted third-party fairness watchdogs. They function as computationally lightweight statistical estimators, and their correctness proofs rely on the rigorous analysis of the stochastic process that models the assumptions about the underlying dynamics of the system. We show, both in theory and experiments, how monitors can warn us (1) if a bank’s credit policy over time has created an unfair distribution of credit scores among the population, and (2) if a resource allocator’s allocation policy over time has made unfair allocations. Our experiments demonstrate that the monitors introduce very low overhead. We believe that runtime monitoring is an important and mathematically rigorous new addition to the fairness toolbox.}, author = {Henzinger, Thomas A and Karimi, Mahyar and Kueffner, Konstantin and Mallik, Kaushik}, booktitle = {FAccT '23: Proceedings of the 2023 ACM Conference on Fairness, Accountability, and Transparency}, isbn = {9781450372527}, location = {Chicago, IL, United States}, pages = {604--614}, publisher = {Association for Computing Machinery}, title = {{Runtime monitoring of dynamic fairness properties}}, doi = {10.1145/3593013.3594028}, year = {2023}, } @article{13225, abstract = {Recently the leading order of the correlation energy of a Fermi gas in a coupled mean-field and semiclassical scaling regime has been derived, under the assumption of an interaction potential with a small norm and with compact support in Fourier space. We generalize this result to large interaction potentials, requiring only |⋅|V^∈ℓ1(Z3). Our proof is based on approximate, collective bosonization in three dimensions. Significant improvements compared to recent work include stronger bounds on non-bosonizable terms and more efficient control on the bosonization of the kinetic energy.}, author = {Benedikter, Niels P and Porta, Marcello and Schlein, Benjamin and Seiringer, Robert}, issn = {1432-0673}, journal = {Archive for Rational Mechanics and Analysis}, number = {4}, publisher = {Springer Nature}, title = {{Correlation energy of a weakly interacting Fermi gas with large interaction potential}}, doi = {10.1007/s00205-023-01893-6}, volume = {247}, year = {2023}, } @article{13226, abstract = {We consider the ground state and the low-energy excited states of a system of N identical bosons with interactions in the mean-field scaling regime. For the ground state, we derive a weak Edgeworth expansion for the fluctuations of bounded one-body operators, which yields corrections to a central limit theorem to any order in 1/N−−√. For suitable excited states, we show that the limiting distribution is a polynomial times a normal distribution, and that higher-order corrections are given by an Edgeworth-type expansion.}, author = {Bossmann, Lea and Petrat, Sören P}, issn = {1573-0530}, journal = {Letters in Mathematical Physics}, number = {4}, publisher = {Springer Nature}, title = {{Weak Edgeworth expansion for the mean-field Bose gas}}, doi = {10.1007/s11005-023-01698-4}, volume = {113}, year = {2023}, } @article{13227, abstract = {Currently available quantum processors are dominated by noise, which severely limits their applicability and motivates the search for new physical qubit encodings. In this work, we introduce the inductively shunted transmon, a weakly flux-tunable superconducting qubit that offers charge offset protection for all levels and a 20-fold reduction in flux dispersion compared to the state-of-the-art resulting in a constant coherence over a full flux quantum. The parabolic confinement provided by the inductive shunt as well as the linearity of the geometric superinductor facilitates a high-power readout that resolves quantum jumps with a fidelity and QND-ness of >90% and without the need for a Josephson parametric amplifier. Moreover, the device reveals quantum tunneling physics between the two prepared fluxon ground states with a measured average decay time of up to 3.5 h. In the future, fast time-domain control of the transition matrix elements could offer a new path forward to also achieve full qubit control in the decay-protected fluxon basis.}, author = {Hassani, Farid and Peruzzo, Matilda and Kapoor, Lucky and Trioni, Andrea and Zemlicka, Martin and Fink, Johannes M}, issn = {2041-1723}, journal = {Nature Communications}, publisher = {Springer Nature}, title = {{Inductively shunted transmons exhibit noise insensitive plasmon states and a fluxon decay exceeding 3 hours}}, doi = {10.1038/s41467-023-39656-2}, volume = {14}, year = {2023}, } @inproceedings{13321, abstract = {We consider the problem of reconstructing the signal and the hidden variables from observations coming from a multi-layer network with rotationally invariant weight matrices. The multi-layer structure models inference from deep generative priors, and the rotational invariance imposed on the weights generalizes the i.i.d. Gaussian assumption by allowing for a complex correlation structure, which is typical in applications. In this work, we present a new class of approximate message passing (AMP) algorithms and give a state evolution recursion which precisely characterizes their performance in the large system limit. In contrast with the existing multi-layer VAMP (ML-VAMP) approach, our proposed AMP – dubbed multilayer rotationally invariant generalized AMP (ML-RI-GAMP) – provides a natural generalization beyond Gaussian designs, in the sense that it recovers the existing Gaussian AMP as a special case. Furthermore, ML-RI-GAMP exhibits a significantly lower complexity than ML-VAMP, as the computationally intensive singular value decomposition is replaced by an estimation of the moments of the design matrices. Finally, our numerical results show that this complexity gain comes at little to no cost in the performance of the algorithm.}, author = {Xu, Yizhou and Hou, Tian Qi and Liang, Shan Suo and Mondelli, Marco}, booktitle = {2023 IEEE Information Theory Workshop}, isbn = {9798350301496}, issn = {2475-4218}, location = {Saint-Malo, France}, pages = {294--298}, publisher = {Institute of Electrical and Electronics Engineers}, title = {{Approximate message passing for multi-layer estimation in rotationally invariant models}}, doi = {10.1109/ITW55543.2023.10160238}, year = {2023}, }