---
_id: '11898'
abstract:
- lang: eng
text: "We build upon the recent papers by Weinstein and Yu (FOCS'16), Larsen (FOCS'12),
and Clifford et al. (FOCS'15) to present a general framework that gives amortized
lower bounds on the update and query times of dynamic data structures. Using our
framework, we present two concrete results.\r\n(1) For the dynamic polynomial
evaluation problem, where the polynomial is defined over a finite field of size
n1+Ω(1) and has degree n, any dynamic data structure must either have an amortized
update time of Ω((lgn/lglgn)2) or an amortized query time of Ω((lgn/lglgn)2).\r\n(2)
For the dynamic online matrix vector multiplication problem, where we get an n×n
matrix whose entires are drawn from a finite field of size nΘ(1), any dynamic
data structure must either have an amortized update time of Ω((lgn/lglgn)2) or
an amortized query time of Ω(n⋅(lgn/lglgn)2).\r\nFor these two problems, the previous
works by Larsen (FOCS'12) and Clifford et al. (FOCS'15) gave the same lower bounds,
but only for worst case update and query times. Our bounds match the highest unconditional
lower bounds known till date for any dynamic problem in the cell-probe model."
article_processing_charge: No
article_type: original
author:
- first_name: Sayan
full_name: Bhattacharya, Sayan
last_name: Bhattacharya
- first_name: Monika H
full_name: Henzinger, Monika H
id: 540c9bbd-f2de-11ec-812d-d04a5be85630
last_name: Henzinger
orcid: 0000-0002-5008-6530
- first_name: Stefan
full_name: Neumann, Stefan
last_name: Neumann
citation:
ama: Bhattacharya S, Henzinger MH, Neumann S. New amortized cell-probe lower bounds
for dynamic problems. Theoretical Computer Science. 2019;779:72-87. doi:10.1016/j.tcs.2019.01.043
apa: Bhattacharya, S., Henzinger, M. H., & Neumann, S. (2019). New amortized
cell-probe lower bounds for dynamic problems. Theoretical Computer Science.
Elsevier. https://doi.org/10.1016/j.tcs.2019.01.043
chicago: Bhattacharya, Sayan, Monika H Henzinger, and Stefan Neumann. “New Amortized
Cell-Probe Lower Bounds for Dynamic Problems.” Theoretical Computer Science.
Elsevier, 2019. https://doi.org/10.1016/j.tcs.2019.01.043.
ieee: S. Bhattacharya, M. H. Henzinger, and S. Neumann, “New amortized cell-probe
lower bounds for dynamic problems,” Theoretical Computer Science, vol.
779. Elsevier, pp. 72–87, 2019.
ista: Bhattacharya S, Henzinger MH, Neumann S. 2019. New amortized cell-probe lower
bounds for dynamic problems. Theoretical Computer Science. 779, 72–87.
mla: Bhattacharya, Sayan, et al. “New Amortized Cell-Probe Lower Bounds for Dynamic
Problems.” Theoretical Computer Science, vol. 779, Elsevier, 2019, pp.
72–87, doi:10.1016/j.tcs.2019.01.043.
short: S. Bhattacharya, M.H. Henzinger, S. Neumann, Theoretical Computer Science
779 (2019) 72–87.
date_created: 2022-08-17T09:02:15Z
date_published: 2019-08-02T00:00:00Z
date_updated: 2022-09-09T11:29:04Z
day: '02'
doi: 10.1016/j.tcs.2019.01.043
extern: '1'
external_id:
arxiv:
- '1902.02304'
intvolume: ' 779'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://arxiv.org/abs/1902.02304
month: '08'
oa: 1
oa_version: Preprint
page: 72-87
publication: Theoretical Computer Science
publication_identifier:
issn:
- 0304-3975
publication_status: published
publisher: Elsevier
quality_controlled: '1'
scopus_import: '1'
status: public
title: New amortized cell-probe lower bounds for dynamic problems
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 779
year: '2019'
...
---
_id: '11957'
abstract:
- lang: eng
text: Cross-coupling reactions mediated by dual nickel/photocatalysis are synthetically
attractive but rely mainly on expensive, non-recyclable noble-metal complexes
as photocatalysts. Heterogeneous semiconductors, which are commonly used for artificial
photosynthesis and wastewater treatment, are a sustainable alternative. Graphitic
carbon nitrides, a class of metal-free polymers that can be easily prepared from
bulk chemicals, are heterogeneous semiconductors with high potential for photocatalytic
organic transformations. Here, we demonstrate that graphitic carbon nitrides in
combination with nickel catalysis can induce selective C−O cross-couplings of
carboxylic acids with aryl halides, yielding the respective aryl esters in excellent
yield and selectivity. The heterogeneous organic photocatalyst exhibits a broad
substrate scope, is able to harvest green light, and can be recycled multiple
times. In situ FTIR was used to track the reaction progress to study this transformation
at different irradiation wavelengths and reaction scales.
article_processing_charge: No
article_type: letter_note
author:
- first_name: Bartholomäus
full_name: Pieber, Bartholomäus
id: 93e5e5b2-0da6-11ed-8a41-af589a024726
last_name: Pieber
orcid: 0000-0001-8689-388X
- first_name: Jamal A.
full_name: Malik, Jamal A.
last_name: Malik
- first_name: Cristian
full_name: Cavedon, Cristian
last_name: Cavedon
- first_name: Sebastian
full_name: Gisbertz, Sebastian
last_name: Gisbertz
- first_name: Aleksandr
full_name: Savateev, Aleksandr
last_name: Savateev
- first_name: Daniel
full_name: Cruz, Daniel
last_name: Cruz
- first_name: Tobias
full_name: Heil, Tobias
last_name: Heil
- first_name: Guigang
full_name: Zhang, Guigang
last_name: Zhang
- first_name: Peter H.
full_name: Seeberger, Peter H.
last_name: Seeberger
citation:
ama: 'Pieber B, Malik JA, Cavedon C, et al. Semi‐heterogeneous dual nickel/photocatalysis
using carbon nitrides: Esterification of carboxylic acids with aryl halides. Angewandte
Chemie International Edition. 2019;58(28):9575-9580. doi:10.1002/anie.201902785'
apa: 'Pieber, B., Malik, J. A., Cavedon, C., Gisbertz, S., Savateev, A., Cruz, D.,
… Seeberger, P. H. (2019). Semi‐heterogeneous dual nickel/photocatalysis using
carbon nitrides: Esterification of carboxylic acids with aryl halides. Angewandte
Chemie International Edition. Wiley. https://doi.org/10.1002/anie.201902785'
chicago: 'Pieber, Bartholomäus, Jamal A. Malik, Cristian Cavedon, Sebastian Gisbertz,
Aleksandr Savateev, Daniel Cruz, Tobias Heil, Guigang Zhang, and Peter H. Seeberger.
“Semi‐heterogeneous Dual Nickel/Photocatalysis Using Carbon Nitrides: Esterification
of Carboxylic Acids with Aryl Halides.” Angewandte Chemie International Edition.
Wiley, 2019. https://doi.org/10.1002/anie.201902785.'
ieee: 'B. Pieber et al., “Semi‐heterogeneous dual nickel/photocatalysis using
carbon nitrides: Esterification of carboxylic acids with aryl halides,” Angewandte
Chemie International Edition, vol. 58, no. 28. Wiley, pp. 9575–9580, 2019.'
ista: 'Pieber B, Malik JA, Cavedon C, Gisbertz S, Savateev A, Cruz D, Heil T, Zhang
G, Seeberger PH. 2019. Semi‐heterogeneous dual nickel/photocatalysis using carbon
nitrides: Esterification of carboxylic acids with aryl halides. Angewandte Chemie
International Edition. 58(28), 9575–9580.'
mla: 'Pieber, Bartholomäus, et al. “Semi‐heterogeneous Dual Nickel/Photocatalysis
Using Carbon Nitrides: Esterification of Carboxylic Acids with Aryl Halides.”
Angewandte Chemie International Edition, vol. 58, no. 28, Wiley, 2019,
pp. 9575–80, doi:10.1002/anie.201902785.'
short: B. Pieber, J.A. Malik, C. Cavedon, S. Gisbertz, A. Savateev, D. Cruz, T.
Heil, G. Zhang, P.H. Seeberger, Angewandte Chemie International Edition 58 (2019)
9575–9580.
date_created: 2022-08-24T10:50:19Z
date_published: 2019-07-08T00:00:00Z
date_updated: 2023-02-21T10:09:16Z
day: '08'
doi: 10.1002/anie.201902785
extern: '1'
external_id:
pmid:
- '31050132'
intvolume: ' 58'
issue: '28'
language:
- iso: eng
month: '07'
oa_version: None
page: 9575-9580
pmid: 1
publication: Angewandte Chemie International Edition
publication_identifier:
eissn:
- 1521-3773
issn:
- 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'Semi‐heterogeneous dual nickel/photocatalysis using carbon nitrides: Esterification
of carboxylic acids with aryl halides'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 58
year: '2019'
...
---
_id: '11984'
abstract:
- lang: eng
text: Differentially protected galactosamine building blocks are key components
for the synthesis of human and bacterial oligosaccharides. The azidophenylselenylation
of 3,4,6-tri-O-acetyl-d-galactal provides straightforward access to the corresponding
2-nitrogenated glycoside. Poor reproducibility and the use of azides that lead
to the formation of potentially explosive and toxic species limit the scalability
of this reaction and render it a bottleneck for carbohydrate synthesis. Here,
we present a method for the safe, efficient, and reliable azidophenylselenylation
of 3,4,6-tri-O-acetyl-d-galactal at room temperature, using continuous flow chemistry.
Careful analysis of the transformation resulted in reaction conditions that produce
minimal side products while the reaction time was reduced drastically when compared
to batch reactions. The flow setup is readily scalable to process 5 mmol of galactal
in 3 h, producing 1.2 mmol/h of product.
article_processing_charge: No
article_type: letter_note
author:
- first_name: Mónica
full_name: Guberman, Mónica
last_name: Guberman
- first_name: Bartholomäus
full_name: Pieber, Bartholomäus
id: 93e5e5b2-0da6-11ed-8a41-af589a024726
last_name: Pieber
orcid: 0000-0001-8689-388X
- first_name: Peter H.
full_name: Seeberger, Peter H.
last_name: Seeberger
citation:
ama: Guberman M, Pieber B, Seeberger PH. Safe and scalable continuous flow azidophenylselenylation
of galactal to prepare galactosamine building blocks. Organic Process Research
and Development. 2019;23(12):2764-2770. doi:10.1021/acs.oprd.9b00456
apa: Guberman, M., Pieber, B., & Seeberger, P. H. (2019). Safe and scalable
continuous flow azidophenylselenylation of galactal to prepare galactosamine building
blocks. Organic Process Research and Development. American Chemical Society.
https://doi.org/10.1021/acs.oprd.9b00456
chicago: Guberman, Mónica, Bartholomäus Pieber, and Peter H. Seeberger. “Safe and
Scalable Continuous Flow Azidophenylselenylation of Galactal to Prepare Galactosamine
Building Blocks.” Organic Process Research and Development. American Chemical
Society, 2019. https://doi.org/10.1021/acs.oprd.9b00456.
ieee: M. Guberman, B. Pieber, and P. H. Seeberger, “Safe and scalable continuous
flow azidophenylselenylation of galactal to prepare galactosamine building blocks,”
Organic Process Research and Development, vol. 23, no. 12. American Chemical
Society, pp. 2764–2770, 2019.
ista: Guberman M, Pieber B, Seeberger PH. 2019. Safe and scalable continuous flow
azidophenylselenylation of galactal to prepare galactosamine building blocks.
Organic Process Research and Development. 23(12), 2764–2770.
mla: Guberman, Mónica, et al. “Safe and Scalable Continuous Flow Azidophenylselenylation
of Galactal to Prepare Galactosamine Building Blocks.” Organic Process Research
and Development, vol. 23, no. 12, American Chemical Society, 2019, pp. 2764–70,
doi:10.1021/acs.oprd.9b00456.
short: M. Guberman, B. Pieber, P.H. Seeberger, Organic Process Research and Development
23 (2019) 2764–2770.
date_created: 2022-08-25T11:30:33Z
date_published: 2019-12-20T00:00:00Z
date_updated: 2023-02-21T10:10:23Z
day: '20'
doi: 10.1021/acs.oprd.9b00456
extern: '1'
intvolume: ' 23'
issue: '12'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.1021/acs.oprd.9b00456
month: '12'
oa: 1
oa_version: Published Version
page: 2764-2770
publication: Organic Process Research and Development
publication_identifier:
eissn:
- 1520-586X
issn:
- 1083-6160
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Safe and scalable continuous flow azidophenylselenylation of galactal to prepare
galactosamine building blocks
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 23
year: '2019'
...
---
_id: '11982'
abstract:
- lang: eng
text: A carbon nitride material can be combined with homogeneous nickel catalysts
for light-mediated cross-couplings of aryl bromides with alcohols under mild conditions.
The metal-free heterogeneous semiconductor is fully recyclable and couples a broad
range of electron-poor aryl bromides with primary and secondary alcohols as well
as water. The application for intramolecular reactions and the synthesis of active
pharmaceutical ingredients was demonstrated. The catalytic protocol is applicable
for the coupling of aryl iodides with thiols as well.
article_processing_charge: No
article_type: letter_note
author:
- first_name: Cristian
full_name: Cavedon, Cristian
last_name: Cavedon
- first_name: Amiera
full_name: Madani, Amiera
last_name: Madani
- first_name: Peter H.
full_name: Seeberger, Peter H.
last_name: Seeberger
- first_name: Bartholomäus
full_name: Pieber, Bartholomäus
id: 93e5e5b2-0da6-11ed-8a41-af589a024726
last_name: Pieber
orcid: 0000-0001-8689-388X
citation:
ama: Cavedon C, Madani A, Seeberger PH, Pieber B. Semiheterogeneous dual nickel/photocatalytic
(thio)etherification using carbon nitrides. Organic Letters. 2019;21(13):5331-5334.
doi:10.1021/acs.orglett.9b01957
apa: Cavedon, C., Madani, A., Seeberger, P. H., & Pieber, B. (2019). Semiheterogeneous
dual nickel/photocatalytic (thio)etherification using carbon nitrides. Organic
Letters. American Chemical Society. https://doi.org/10.1021/acs.orglett.9b01957
chicago: Cavedon, Cristian, Amiera Madani, Peter H. Seeberger, and Bartholomäus
Pieber. “Semiheterogeneous Dual Nickel/Photocatalytic (Thio)Etherification Using
Carbon Nitrides.” Organic Letters. American Chemical Society, 2019. https://doi.org/10.1021/acs.orglett.9b01957.
ieee: C. Cavedon, A. Madani, P. H. Seeberger, and B. Pieber, “Semiheterogeneous
dual nickel/photocatalytic (thio)etherification using carbon nitrides,” Organic
Letters, vol. 21, no. 13. American Chemical Society, pp. 5331–5334, 2019.
ista: Cavedon C, Madani A, Seeberger PH, Pieber B. 2019. Semiheterogeneous dual
nickel/photocatalytic (thio)etherification using carbon nitrides. Organic Letters.
21(13), 5331–5334.
mla: Cavedon, Cristian, et al. “Semiheterogeneous Dual Nickel/Photocatalytic (Thio)Etherification
Using Carbon Nitrides.” Organic Letters, vol. 21, no. 13, American Chemical
Society, 2019, pp. 5331–34, doi:10.1021/acs.orglett.9b01957.
short: C. Cavedon, A. Madani, P.H. Seeberger, B. Pieber, Organic Letters 21 (2019)
5331–5334.
date_created: 2022-08-25T11:18:00Z
date_published: 2019-07-05T00:00:00Z
date_updated: 2023-02-21T10:10:19Z
day: '05'
doi: 10.1021/acs.orglett.9b01957
extern: '1'
external_id:
pmid:
- '31247752'
intvolume: ' 21'
issue: '13'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.1021/acs.orglett.9b01957
month: '07'
oa: 1
oa_version: Published Version
page: 5331-5334
pmid: 1
publication: Organic Letters
publication_identifier:
eissn:
- 1523-7052
issn:
- 1523-7060
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Semiheterogeneous dual nickel/photocatalytic (thio)etherification using carbon
nitrides
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 21
year: '2019'
...
---
_id: '170'
abstract:
- lang: eng
text: Upper and lower bounds, of the expected order of magnitude, are obtained for
the number of rational points of bounded height on any quartic del Pezzo surface
over ℚ that contains a conic defined over ℚ .
author:
- first_name: Timothy D
full_name: Browning, Timothy D
id: 35827D50-F248-11E8-B48F-1D18A9856A87
last_name: Browning
orcid: 0000-0002-8314-0177
- first_name: Efthymios
full_name: Sofos, Efthymios
last_name: Sofos
citation:
ama: Browning TD, Sofos E. Counting rational points on quartic del Pezzo surfaces
with a rational conic. Mathematische Annalen. 2019;373(3-4):977-1016. doi:10.1007/s00208-018-1716-6
apa: Browning, T. D., & Sofos, E. (2019). Counting rational points on quartic
del Pezzo surfaces with a rational conic. Mathematische Annalen. Springer
Nature. https://doi.org/10.1007/s00208-018-1716-6
chicago: Browning, Timothy D, and Efthymios Sofos. “Counting Rational Points on
Quartic Del Pezzo Surfaces with a Rational Conic.” Mathematische Annalen.
Springer Nature, 2019. https://doi.org/10.1007/s00208-018-1716-6.
ieee: T. D. Browning and E. Sofos, “Counting rational points on quartic del Pezzo
surfaces with a rational conic,” Mathematische Annalen, vol. 373, no. 3–4.
Springer Nature, pp. 977–1016, 2019.
ista: Browning TD, Sofos E. 2019. Counting rational points on quartic del Pezzo
surfaces with a rational conic. Mathematische Annalen. 373(3–4), 977–1016.
mla: Browning, Timothy D., and Efthymios Sofos. “Counting Rational Points on Quartic
Del Pezzo Surfaces with a Rational Conic.” Mathematische Annalen, vol.
373, no. 3–4, Springer Nature, 2019, pp. 977–1016, doi:10.1007/s00208-018-1716-6.
short: T.D. Browning, E. Sofos, Mathematische Annalen 373 (2019) 977–1016.
date_created: 2018-12-11T11:44:59Z
date_published: 2019-04-01T00:00:00Z
date_updated: 2021-01-12T06:52:37Z
day: '01'
ddc:
- '510'
doi: 10.1007/s00208-018-1716-6
extern: '1'
external_id:
arxiv:
- '1609.09057'
file:
- access_level: open_access
checksum: 4061dc2fe99bee25d9adf2d2018cf608
content_type: application/pdf
creator: dernst
date_created: 2019-05-23T07:53:27Z
date_updated: 2020-07-14T12:45:12Z
file_id: '6479'
file_name: 2019_MathAnnalen_Browning.pdf
file_size: 712847
relation: main_file
file_date_updated: 2020-07-14T12:45:12Z
has_accepted_license: '1'
intvolume: ' 373'
issue: 3-4
language:
- iso: eng
license: https://creativecommons.org/licenses/by/4.0/
month: '04'
oa: 1
oa_version: Published Version
page: 977-1016
publication: Mathematische Annalen
publication_status: published
publisher: Springer Nature
quality_controlled: '1'
status: public
title: Counting rational points on quartic del Pezzo surfaces with a rational conic
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 373
year: '2019'
...