---
_id: '7314'
abstract:
- lang: eng
text: 'The electrolyte is one of the greatest challenges facing the development
of the non‐aqueous Li–O2 battery. Although ether‐based electrolytes do from Li2O2
on the first discharge, it is shown by various techniques that they also decompose
and that decomposition increases while Li2O2 decreases on cycling (see picture).
Thus, these electrolytes are not suitable. '
article_processing_charge: No
article_type: original
author:
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Yuhui
full_name: Chen, Yuhui
last_name: Chen
- first_name: Nicholas E.
full_name: Drewett, Nicholas E.
last_name: Drewett
- first_name: Laurence J.
full_name: Hardwick, Laurence J.
last_name: Hardwick
- first_name: Fanny
full_name: Bardé, Fanny
last_name: Bardé
- first_name: Peter G.
full_name: Bruce, Peter G.
last_name: Bruce
citation:
ama: Freunberger SA, Chen Y, Drewett NE, Hardwick LJ, Bardé F, Bruce PG. The Lithium-Oxygen
battery with ether-based electrolytes. Angewandte Chemie International Edition.
2011;50(37):8609-8613. doi:10.1002/anie.201102357
apa: Freunberger, S. A., Chen, Y., Drewett, N. E., Hardwick, L. J., Bardé, F., &
Bruce, P. G. (2011). The Lithium-Oxygen battery with ether-based electrolytes.
Angewandte Chemie International Edition. Wiley. https://doi.org/10.1002/anie.201102357
chicago: Freunberger, Stefan Alexander, Yuhui Chen, Nicholas E. Drewett, Laurence
J. Hardwick, Fanny Bardé, and Peter G. Bruce. “The Lithium-Oxygen Battery with
Ether-Based Electrolytes.” Angewandte Chemie International Edition. Wiley,
2011. https://doi.org/10.1002/anie.201102357.
ieee: S. A. Freunberger, Y. Chen, N. E. Drewett, L. J. Hardwick, F. Bardé, and P.
G. Bruce, “The Lithium-Oxygen battery with ether-based electrolytes,” Angewandte
Chemie International Edition, vol. 50, no. 37. Wiley, pp. 8609–8613, 2011.
ista: Freunberger SA, Chen Y, Drewett NE, Hardwick LJ, Bardé F, Bruce PG. 2011.
The Lithium-Oxygen battery with ether-based electrolytes. Angewandte Chemie International
Edition. 50(37), 8609–8613.
mla: Freunberger, Stefan Alexander, et al. “The Lithium-Oxygen Battery with Ether-Based
Electrolytes.” Angewandte Chemie International Edition, vol. 50, no. 37,
Wiley, 2011, pp. 8609–13, doi:10.1002/anie.201102357.
short: S.A. Freunberger, Y. Chen, N.E. Drewett, L.J. Hardwick, F. Bardé, P.G. Bruce,
Angewandte Chemie International Edition 50 (2011) 8609–8613.
date_created: 2020-01-15T12:20:19Z
date_published: 2011-09-05T00:00:00Z
date_updated: 2021-01-12T08:12:59Z
day: '05'
doi: 10.1002/anie.201102357
extern: '1'
intvolume: ' 50'
issue: '37'
language:
- iso: eng
month: '09'
oa_version: None
page: 8609-8613
publication: Angewandte Chemie International Edition
publication_identifier:
issn:
- 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: The Lithium-Oxygen battery with ether-based electrolytes
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 50
year: '2011'
...
---
_id: '7317'
abstract:
- lang: eng
text: Lithium-metal oxides with a high formal Li2O content, such as Li5FeO4 (5Li2O•Fe2O3)
and a Li2MnO3•LiFeO2 composite ({Li2O•MnO2}•{Li2O•Fe2O3}) have been explored as
electrocatalysts for primary and rechargeable Li-O2 cells. Activation occurs predominantly
by Li2O removal, either electrochemically or chemically by acid-treatment. Superior
electrochemical behavior is obtained if activation occurs by acid-treatment; Li2MnO3•LiFeO2
catalysts provide 2516 mAh/g (carbon) corresponding to 931 mAh/g (electrocatalyst
+ carbon) during the initial discharge. The reaction is reasonably reversible
during the early cycles. The approach has implications for designing electrocatalysts
that participate through electrochemical Li2O extraction/reformation reactions,
offering exceptionally high capacities.
article_number: A64
article_processing_charge: No
article_type: original
author:
- first_name: L.
full_name: Trahey, L.
last_name: Trahey
- first_name: C. S.
full_name: Johnson, C. S.
last_name: Johnson
- first_name: J. T.
full_name: Vaughey, J. T.
last_name: Vaughey
- first_name: S.-H.
full_name: Kang, S.-H.
last_name: Kang
- first_name: L. J.
full_name: Hardwick, L. J.
last_name: Hardwick
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: P. G.
full_name: Bruce, P. G.
last_name: Bruce
- first_name: M. M.
full_name: Thackeray, M. M.
last_name: Thackeray
citation:
ama: Trahey L, Johnson CS, Vaughey JT, et al. Activated Lithium-Metal-Oxides as
catalytic electrodes for Li–O2 cells. Electrochemical and Solid-State Letters.
2011;14(5). doi:10.1149/1.3555366
apa: Trahey, L., Johnson, C. S., Vaughey, J. T., Kang, S.-H., Hardwick, L. J., Freunberger,
S. A., … Thackeray, M. M. (2011). Activated Lithium-Metal-Oxides as catalytic
electrodes for Li–O2 cells. Electrochemical and Solid-State Letters. The
Electrochemical Society. https://doi.org/10.1149/1.3555366
chicago: Trahey, L., C. S. Johnson, J. T. Vaughey, S.-H. Kang, L. J. Hardwick, Stefan
Alexander Freunberger, P. G. Bruce, and M. M. Thackeray. “Activated Lithium-Metal-Oxides
as Catalytic Electrodes for Li–O2 Cells.” Electrochemical and Solid-State Letters.
The Electrochemical Society, 2011. https://doi.org/10.1149/1.3555366.
ieee: L. Trahey et al., “Activated Lithium-Metal-Oxides as catalytic electrodes
for Li–O2 cells,” Electrochemical and Solid-State Letters, vol. 14, no.
5. The Electrochemical Society, 2011.
ista: Trahey L, Johnson CS, Vaughey JT, Kang S-H, Hardwick LJ, Freunberger SA, Bruce
PG, Thackeray MM. 2011. Activated Lithium-Metal-Oxides as catalytic electrodes
for Li–O2 cells. Electrochemical and Solid-State Letters. 14(5), A64.
mla: Trahey, L., et al. “Activated Lithium-Metal-Oxides as Catalytic Electrodes
for Li–O2 Cells.” Electrochemical and Solid-State Letters, vol. 14, no.
5, A64, The Electrochemical Society, 2011, doi:10.1149/1.3555366.
short: L. Trahey, C.S. Johnson, J.T. Vaughey, S.-H. Kang, L.J. Hardwick, S.A. Freunberger,
P.G. Bruce, M.M. Thackeray, Electrochemical and Solid-State Letters 14 (2011).
date_created: 2020-01-15T12:20:54Z
date_published: 2011-03-02T00:00:00Z
date_updated: 2021-01-12T08:13:00Z
day: '02'
doi: 10.1149/1.3555366
extern: '1'
intvolume: ' 14'
issue: '5'
language:
- iso: eng
month: '03'
oa_version: None
publication: Electrochemical and Solid-State Letters
publication_identifier:
issn:
- 1099-0062
publication_status: published
publisher: The Electrochemical Society
quality_controlled: '1'
status: public
title: Activated Lithium-Metal-Oxides as catalytic electrodes for Li–O2 cells
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 14
year: '2011'
...
---
_id: '7316'
abstract:
- lang: eng
text: The nonaqueous rechargeable lithium–O2 battery containing an alkyl carbonate
electrolyte discharges by formation of C3H6(OCO2Li)2, Li2CO3, HCO2Li, CH3CO2Li,
CO2, and H2O at the cathode, due to electrolyte decomposition. Charging involves
oxidation of C3H6(OCO2Li)2, Li2CO3, HCO2Li, CH3CO2Li accompanied by CO2 and H2O
evolution. Mechanisms are proposed for the reactions on discharge and charge.
The different pathways for discharge and charge are consistent with the widely
observed voltage gap in Li–O2 cells. Oxidation of C3H6(OCO2Li)2 involves terminal
carbonate groups leaving behind the OC3H6O moiety that reacts to form a thick
gel on the Li anode. Li2CO3, HCO2Li, CH3CO2Li, and C3H6(OCO2Li)2 accumulate in
the cathode on cycling correlating with capacity fading and cell failure. The
latter is compounded by continuous consumption of the electrolyte on each discharge.
article_processing_charge: No
article_type: original
author:
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Yuhui
full_name: Chen, Yuhui
last_name: Chen
- first_name: Zhangquan
full_name: Peng, Zhangquan
last_name: Peng
- first_name: John M.
full_name: Griffin, John M.
last_name: Griffin
- first_name: Laurence J.
full_name: Hardwick, Laurence J.
last_name: Hardwick
- first_name: Fanny
full_name: Bardé, Fanny
last_name: Bardé
- first_name: Petr
full_name: Novák, Petr
last_name: Novák
- first_name: Peter G.
full_name: Bruce, Peter G.
last_name: Bruce
citation:
ama: Freunberger SA, Chen Y, Peng Z, et al. Reactions in the rechargeable Lithium–O2
battery with alkyl carbonate electrolytes. Journal of the American Chemical
Society. 2011;133(20):8040-8047. doi:10.1021/ja2021747
apa: Freunberger, S. A., Chen, Y., Peng, Z., Griffin, J. M., Hardwick, L. J., Bardé,
F., … Bruce, P. G. (2011). Reactions in the rechargeable Lithium–O2 battery with
alkyl carbonate electrolytes. Journal of the American Chemical Society.
ACS. https://doi.org/10.1021/ja2021747
chicago: Freunberger, Stefan Alexander, Yuhui Chen, Zhangquan Peng, John M. Griffin,
Laurence J. Hardwick, Fanny Bardé, Petr Novák, and Peter G. Bruce. “Reactions
in the Rechargeable Lithium–O2 Battery with Alkyl Carbonate Electrolytes.” Journal
of the American Chemical Society. ACS, 2011. https://doi.org/10.1021/ja2021747.
ieee: S. A. Freunberger et al., “Reactions in the rechargeable Lithium–O2
battery with alkyl carbonate electrolytes,” Journal of the American Chemical
Society, vol. 133, no. 20. ACS, pp. 8040–8047, 2011.
ista: Freunberger SA, Chen Y, Peng Z, Griffin JM, Hardwick LJ, Bardé F, Novák
P, Bruce PG. 2011. Reactions in the rechargeable Lithium–O2 battery with alkyl
carbonate electrolytes. Journal of the American Chemical Society. 133(20), 8040–8047.
mla: Freunberger, Stefan Alexander, et al. “Reactions in the Rechargeable Lithium–O2
Battery with Alkyl Carbonate Electrolytes.” Journal of the American Chemical
Society, vol. 133, no. 20, ACS, 2011, pp. 8040–47, doi:10.1021/ja2021747.
short: S.A. Freunberger, Y. Chen, Z. Peng, J.M. Griffin, L.J. Hardwick, F. Bardé,
P. Novák, P.G. Bruce, Journal of the American Chemical Society 133 (2011) 8040–8047.
date_created: 2020-01-15T12:20:43Z
date_published: 2011-04-27T00:00:00Z
date_updated: 2021-01-12T08:13:00Z
day: '27'
doi: 10.1021/ja2021747
extern: '1'
intvolume: ' 133'
issue: '20'
language:
- iso: eng
month: '04'
oa_version: None
page: 8040-8047
publication: Journal of the American Chemical Society
publication_identifier:
issn:
- 0002-7863
- 1520-5126
publication_status: published
publisher: ACS
quality_controlled: '1'
status: public
title: Reactions in the rechargeable Lithium–O2 battery with alkyl carbonate electrolytes
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 133
year: '2011'
...
---
_id: '7315'
abstract:
- lang: eng
text: 'Spectroscopic data (see picture) provide direct evidence that in non‐aqueous
Li+ electrolyte, O2 is reduced to O2−, which then forms LiO2 on the electrode
surface which disproportionates to Li2O2. On charging, Li2O2 decomposes directly,
in a one‐step reaction to evolve O2 and does not pass through LiO2 as an intermediate. '
article_processing_charge: No
article_type: original
author:
- first_name: Zhangquan
full_name: Peng, Zhangquan
last_name: Peng
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Laurence J.
full_name: Hardwick, Laurence J.
last_name: Hardwick
- first_name: Yuhui
full_name: Chen, Yuhui
last_name: Chen
- first_name: Vincent
full_name: Giordani, Vincent
last_name: Giordani
- first_name: Fanny
full_name: Bardé, Fanny
last_name: Bardé
- first_name: Petr
full_name: Novák, Petr
last_name: Novák
- first_name: Duncan
full_name: Graham, Duncan
last_name: Graham
- first_name: Jean-Marie
full_name: Tarascon, Jean-Marie
last_name: Tarascon
- first_name: Peter G.
full_name: Bruce, Peter G.
last_name: Bruce
citation:
ama: Peng Z, Freunberger SA, Hardwick LJ, et al. Oxygen reactions in a non-aqueous
Li+ electrolyte. Angewandte Chemie International Edition. 2011;50(28):6351-6355.
doi:10.1002/anie.201100879
apa: Peng, Z., Freunberger, S. A., Hardwick, L. J., Chen, Y., Giordani, V., Bardé,
F., … Bruce, P. G. (2011). Oxygen reactions in a non-aqueous Li+ electrolyte.
Angewandte Chemie International Edition. Wiley. https://doi.org/10.1002/anie.201100879
chicago: Peng, Zhangquan, Stefan Alexander Freunberger, Laurence J. Hardwick, Yuhui
Chen, Vincent Giordani, Fanny Bardé, Petr Novák, Duncan Graham, Jean-Marie Tarascon,
and Peter G. Bruce. “Oxygen Reactions in a Non-Aqueous Li+ Electrolyte.” Angewandte
Chemie International Edition. Wiley, 2011. https://doi.org/10.1002/anie.201100879.
ieee: Z. Peng et al., “Oxygen reactions in a non-aqueous Li+ electrolyte,”
Angewandte Chemie International Edition, vol. 50, no. 28. Wiley, pp. 6351–6355,
2011.
ista: Peng Z, Freunberger SA, Hardwick LJ, Chen Y, Giordani V, Bardé F, Novák P,
Graham D, Tarascon J-M, Bruce PG. 2011. Oxygen reactions in a non-aqueous Li+
electrolyte. Angewandte Chemie International Edition. 50(28), 6351–6355.
mla: Peng, Zhangquan, et al. “Oxygen Reactions in a Non-Aqueous Li+ Electrolyte.”
Angewandte Chemie International Edition, vol. 50, no. 28, Wiley, 2011,
pp. 6351–55, doi:10.1002/anie.201100879.
short: Z. Peng, S.A. Freunberger, L.J. Hardwick, Y. Chen, V. Giordani, F. Bardé,
P. Novák, D. Graham, J.-M. Tarascon, P.G. Bruce, Angewandte Chemie International
Edition 50 (2011) 6351–6355.
date_created: 2020-01-15T12:20:31Z
date_published: 2011-07-04T00:00:00Z
date_updated: 2021-01-12T08:12:59Z
day: '04'
doi: 10.1002/anie.201100879
extern: '1'
intvolume: ' 50'
issue: '28'
language:
- iso: eng
month: '07'
oa_version: None
page: 6351-6355
publication: Angewandte Chemie International Edition
publication_identifier:
issn:
- 1433-7851
publication_status: published
publisher: Wiley
status: public
title: Oxygen reactions in a non-aqueous Li+ electrolyte
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 50
year: '2011'
...
---
_id: '757'
abstract:
- lang: eng
text: Synchronous distributed algorithms are easier to design and prove correct
than algorithms that tolerate asynchrony. Yet, in the real world, networks experience
asynchrony and other timing anomalies. In this paper, we address the question
of how to efficiently transform an algorithm that relies on synchronization into
an algorithm that tolerates asynchronous executions. We introduce a transformation
technique from synchronous algorithms to indulgent algorithms [1], which induces
only a constant overhead in terms of time complexity in well-behaved executions.
Our technique is based on a new abstraction we call an asynchrony detector, which
the participating processes implement collectively. The resulting transformation
works for a large class of colorless tasks, including consensus and set agreement.
Interestingly, we also show that our technique is relevant for colored tasks,
by applying it to the renaming problem, to obtain the first indulgent renaming
algorithm.
acknowledgement: "The authors would like to thank Prof. Hagit Attiya and Nikola\r\nKneˇ\r\nzevi
́\r\nc for their help on previous drafts of this paper, and the anonymous reviewers\r\nfor
their useful feedback."
alternative_title:
- LNCS
article_processing_charge: No
author:
- first_name: Dan-Adrian
full_name: Alistarh, Dan-Adrian
id: 4A899BFC-F248-11E8-B48F-1D18A9856A87
last_name: Alistarh
orcid: 0000-0003-3650-940X
- first_name: Seth
full_name: Gilbert, Seth
last_name: Gilbert
- first_name: Rachid
full_name: Guerraoui, Rachid
last_name: Guerraoui
- first_name: Corentin
full_name: Travers, Corentin
last_name: Travers
citation:
ama: 'Alistarh D-A, Gilbert S, Guerraoui R, Travers C. Generating fast indulgent
algorithms. In: Vol 6522 LNCS. Springer; 2011:41-52. doi:10.1007/978-3-642-17679-1_4'
apa: 'Alistarh, D.-A., Gilbert, S., Guerraoui, R., & Travers, C. (2011). Generating
fast indulgent algorithms (Vol. 6522 LNCS, pp. 41–52). Presented at the ICDCN:
International Conference on Distributed Computing and Networking, Springer. https://doi.org/10.1007/978-3-642-17679-1_4'
chicago: Alistarh, Dan-Adrian, Seth Gilbert, Rachid Guerraoui, and Corentin Travers.
“Generating Fast Indulgent Algorithms,” 6522 LNCS:41–52. Springer, 2011. https://doi.org/10.1007/978-3-642-17679-1_4.
ieee: 'D.-A. Alistarh, S. Gilbert, R. Guerraoui, and C. Travers, “Generating fast
indulgent algorithms,” presented at the ICDCN: International Conference on Distributed
Computing and Networking, 2011, vol. 6522 LNCS, pp. 41–52.'
ista: 'Alistarh D-A, Gilbert S, Guerraoui R, Travers C. 2011. Generating fast indulgent
algorithms. ICDCN: International Conference on Distributed Computing and Networking,
LNCS, vol. 6522 LNCS, 41–52.'
mla: Alistarh, Dan-Adrian, et al. Generating Fast Indulgent Algorithms. Vol.
6522 LNCS, Springer, 2011, pp. 41–52, doi:10.1007/978-3-642-17679-1_4.
short: D.-A. Alistarh, S. Gilbert, R. Guerraoui, C. Travers, in:, Springer, 2011,
pp. 41–52.
conference:
name: 'ICDCN: International Conference on Distributed Computing and Networking'
date_created: 2018-12-11T11:48:20Z
date_published: 2011-01-01T00:00:00Z
date_updated: 2023-02-23T13:11:09Z
day: '01'
doi: 10.1007/978-3-642-17679-1_4
extern: '1'
language:
- iso: eng
month: '01'
oa_version: None
page: 41 - 52
publication_status: published
publisher: Springer
publist_id: '6898'
status: public
title: Generating fast indulgent algorithms
type: conference
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 6522 LNCS
year: '2011'
...