[{"oa_version":"Published Version","file":[{"access_level":"open_access","file_name":"2023_npjclimate_Goswami.pdf","creator":"dernst","file_size":1750712,"content_type":"application/pdf","file_id":"13326","relation":"main_file","success":1,"checksum":"e9967d436a83b8ffcc6f58782e1f7500","date_updated":"2023-07-31T08:00:01Z","date_created":"2023-07-31T08:00:01Z"}],"intvolume":" 6","title":"An assessment of the ENSO-monsoon teleconnection in a warming climate","ddc":["550"],"status":"public","_id":"13256","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","abstract":[{"text":"The El Niño-Southern Oscillation (ENSO) and the Indian summer monsoon (ISM, or monsoon) are two giants of tropical climate. Here we assess the future evolution of the ENSO-monsoon teleconnection in climate simulations with idealized forcing of CO2 increment at a rate of 1% year-1 starting from a present-day condition (367 p.p.m.) until quadrupling. We find a monotonous weakening of the ENSO-monsoon teleconnection with the increase in CO2. Increased co-occurrences of El Niño and positive Indian Ocean Dipoles (pIODs) in a warmer climate weaken the teleconnection. Co-occurrences of El Niño and pIOD are attributable to mean sea surface temperature (SST) warming that resembles a pIOD-type warming pattern in the Indian Ocean and an El Niño-type warming in the Pacific. Since ENSO is a critical precursor of the strength of the Indian monsoon, a weakening of this relation may mean a less predictable Indian monsoon in a warmer climate.","lang":"eng"}],"type":"journal_article","date_published":"2023-07-08T00:00:00Z","article_type":"original","citation":{"chicago":"GOSWAMI, BIDYUT B, and Soon Il An. “An Assessment of the ENSO-Monsoon Teleconnection in a Warming Climate.” Npj Climate and Atmospheric Science. Springer Nature, 2023. https://doi.org/10.1038/s41612-023-00411-5.","short":"B.B. GOSWAMI, S.I. An, Npj Climate and Atmospheric Science 6 (2023).","mla":"GOSWAMI, BIDYUT B., and Soon Il An. “An Assessment of the ENSO-Monsoon Teleconnection in a Warming Climate.” Npj Climate and Atmospheric Science, vol. 6, 82, Springer Nature, 2023, doi:10.1038/s41612-023-00411-5.","apa":"GOSWAMI, B. B., & An, S. I. (2023). An assessment of the ENSO-monsoon teleconnection in a warming climate. Npj Climate and Atmospheric Science. Springer Nature. https://doi.org/10.1038/s41612-023-00411-5","ieee":"B. B. GOSWAMI and S. I. An, “An assessment of the ENSO-monsoon teleconnection in a warming climate,” npj Climate and Atmospheric Science, vol. 6. Springer Nature, 2023.","ista":"GOSWAMI BB, An SI. 2023. An assessment of the ENSO-monsoon teleconnection in a warming climate. npj Climate and Atmospheric Science. 6, 82.","ama":"GOSWAMI BB, An SI. An assessment of the ENSO-monsoon teleconnection in a warming climate. npj Climate and Atmospheric Science. 2023;6. doi:10.1038/s41612-023-00411-5"},"publication":"npj Climate and Atmospheric Science","article_processing_charge":"Yes","has_accepted_license":"1","day":"08","scopus_import":"1","volume":6,"date_updated":"2023-08-02T06:38:07Z","date_created":"2023-07-23T22:01:10Z","author":[{"full_name":"Goswami, Bidyut B","last_name":"Goswami","first_name":"Bidyut B","id":"3a4ac09c-6d61-11ec-bf66-884cde66b64b"},{"full_name":"An, Soon Il","first_name":"Soon Il","last_name":"An"}],"publisher":"Springer Nature","department":[{"_id":"CaMu"}],"publication_status":"published","year":"2023","acknowledgement":"This work was supported by National Research Foundation of Korea (NRF) grants funded by the Korean government (MSIT) (NRF-2018R1A5A1024958, RS-2023-00208000). Model simulation and data transfer were supported by the National Supercomputing Center with supercomputing resources including technical support (KSC-2019-CHA-0005), the National Center for Meteorological Supercomputer of the Korea Meteorological Administration (KMA), and by the Korea Research Environment Open NETwork (KREONET), respectively. We sincerely thank Dr. Jongsoo Shin of Pohang University of Science and Technology, Pohang, South Korea for the model simulations.","license":"https://creativecommons.org/licenses/by/4.0/","file_date_updated":"2023-07-31T08:00:01Z","article_number":"82","language":[{"iso":"eng"}],"doi":"10.1038/s41612-023-00411-5","isi":1,"quality_controlled":"1","external_id":{"isi":["001024920300002"]},"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png"},"oa":1,"publication_identifier":{"eissn":["2397-3722"]},"month":"07"},{"quality_controlled":"1","isi":1,"external_id":{"pmid":["37341535"],"isi":["001023444700003"]},"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png"},"oa":1,"language":[{"iso":"eng"}],"doi":"10.1093/gbe/evad113","publication_identifier":{"eissn":["1759-6653"]},"month":"07","department":[{"_id":"BeVi"}],"publisher":"Oxford Academic","publication_status":"published","pmid":1,"year":"2023","acknowledgement":"This work was supported by the Vienna Science and Technology Fund (WWTF)(10.47379/MA16061). C.K. received funding from the Royal Society (RG170315) and the Carnegie Trust (RIG007474). M.G.R. and R.R.S. have been supported by NERC (UK) grants NE/I014632/1 and NE/V001566/1. Bioinformatics analyses were performed on the computer cluster at the University of St Andrews Bioinformatics Unit, which is funded by Wellcome Trust ISSF awards 105621/Z/14/Z. Complementary data parsing was carried out with the computational resources provided by the Research/Scientific Computing teams at The James Hutton Institute and the National Institute of Agricultural Botany (NIAB)—UK’s Crop Diversity Bioinformatics HPC, BBSRC grant BB/S019669/1. We are thankful to Paris Veltsos and R. Axel W. Wiberg for useful discussions about the project as well as providing us with the resequencing data they had produced as a result of previous work on this experiment. We are especially grateful to Tanya Sneddon for her help with the DNA extraction process and shipping.","volume":15,"date_created":"2023-07-23T22:01:11Z","date_updated":"2023-08-02T06:42:35Z","related_material":{"link":[{"relation":"software","url":"https://github.com/carolbarata/dpseudo-n-beyond"}]},"author":[{"first_name":"Carolina","last_name":"De Castro Barbosa Rodrigues Barata","id":"20565186-803f-11ed-ab7e-96a4ff7694ef","full_name":"De Castro Barbosa Rodrigues Barata, Carolina"},{"full_name":"Snook, Rhonda R.","last_name":"Snook","first_name":"Rhonda R."},{"full_name":"Ritchie, Michael G.","last_name":"Ritchie","first_name":"Michael G."},{"first_name":"Carolin","last_name":"Kosiol","full_name":"Kosiol, Carolin"}],"article_number":"evad113","file_date_updated":"2023-08-01T06:58:34Z","article_type":"original","citation":{"short":"C. de Castro Barbosa Rodrigues Barata, R.R. Snook, M.G. Ritchie, C. Kosiol, Genome Biology and Evolution 15 (2023).","mla":"de Castro Barbosa Rodrigues Barata, Carolina, et al. “Selection on the Fly: Short-Term Adaptation to an Altered Sexual Selection Regime in Drosophila Pseudoobscura.” Genome Biology and Evolution, vol. 15, no. 7, evad113, Oxford Academic, 2023, doi:10.1093/gbe/evad113.","chicago":"Castro Barbosa Rodrigues Barata, Carolina de, Rhonda R. Snook, Michael G. Ritchie, and Carolin Kosiol. “Selection on the Fly: Short-Term Adaptation to an Altered Sexual Selection Regime in Drosophila Pseudoobscura.” Genome Biology and Evolution. Oxford Academic, 2023. https://doi.org/10.1093/gbe/evad113.","ama":"de Castro Barbosa Rodrigues Barata C, Snook RR, Ritchie MG, Kosiol C. Selection on the fly: Short-term adaptation to an altered sexual selection regime in Drosophila pseudoobscura. Genome biology and evolution. 2023;15(7). doi:10.1093/gbe/evad113","ieee":"C. de Castro Barbosa Rodrigues Barata, R. R. Snook, M. G. Ritchie, and C. Kosiol, “Selection on the fly: Short-term adaptation to an altered sexual selection regime in Drosophila pseudoobscura,” Genome biology and evolution, vol. 15, no. 7. Oxford Academic, 2023.","apa":"de Castro Barbosa Rodrigues Barata, C., Snook, R. R., Ritchie, M. G., & Kosiol, C. (2023). Selection on the fly: Short-term adaptation to an altered sexual selection regime in Drosophila pseudoobscura. Genome Biology and Evolution. Oxford Academic. https://doi.org/10.1093/gbe/evad113","ista":"de Castro Barbosa Rodrigues Barata C, Snook RR, Ritchie MG, Kosiol C. 2023. Selection on the fly: Short-term adaptation to an altered sexual selection regime in Drosophila pseudoobscura. Genome biology and evolution. 15(7), evad113."},"publication":"Genome biology and evolution","date_published":"2023-07-01T00:00:00Z","scopus_import":"1","has_accepted_license":"1","article_processing_charge":"Yes","day":"01","intvolume":" 15","ddc":["570"],"title":"Selection on the fly: Short-term adaptation to an altered sexual selection regime in Drosophila pseudoobscura","status":"public","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","_id":"13260","oa_version":"Published Version","file":[{"access_level":"open_access","file_name":"2023_GBE_Barata.pdf","file_size":2382587,"content_type":"application/pdf","creator":"dernst","relation":"main_file","file_id":"13339","checksum":"70de3c4878de6efe00dc56de2df8812f","success":1,"date_updated":"2023-08-01T06:58:34Z","date_created":"2023-08-01T06:58:34Z"}],"type":"journal_article","issue":"7","abstract":[{"lang":"eng","text":"Experimental evolution studies are powerful approaches to examine the evolutionary history of lab populations. Such studies have shed light on how selection changes phenotypes and genotypes. Most of these studies have not examined the time course of adaptation under sexual selection manipulation, by resequencing the populations’ genomes at multiple time points. Here, we analyze allele frequency trajectories in Drosophila pseudoobscura where we altered their sexual selection regime for 200 generations and sequenced pooled populations at 5 time points. The intensity of sexual selection was either relaxed in monogamous populations (M) or elevated in polyandrous lines (E). We present a comprehensive study of how selection alters population genetics parameters at the chromosome and gene level. We investigate differences in the effective population size—Ne—between the treatments, and perform a genome-wide scan to identify signatures of selection from the time-series data. We found genomic signatures of adaptation to both regimes in D. pseudoobscura. There are more significant variants in E lines as expected from stronger sexual selection. However, we found that the response on the X chromosome was substantial in both treatments, more pronounced in E and restricted to the more recently sex-linked chromosome arm XR in M. In the first generations of experimental evolution, we estimate Ne to be lower on the X in E lines, which might indicate a swift adaptive response at the onset of selection. Additionally, the third chromosome was affected by elevated polyandry whereby its distal end harbors a region showing a strong signal of adaptive evolution especially in E lines."}]},{"oa":1,"main_file_link":[{"open_access":"1","url":"https://doi.org/10.1021/acsnano.2c07558"}],"quality_controlled":"1","doi":"10.1021/acsnano.2c07558","language":[{"iso":"eng"}],"month":"01","publication_identifier":{"issn":["1936-0851"],"eissn":["1936-086X"]},"year":"2023","publication_status":"published","publisher":"American Chemical Society","author":[{"first_name":"Chiara","last_name":"Lionello","full_name":"Lionello, Chiara"},{"first_name":"Claudio","last_name":"Perego","full_name":"Perego, Claudio"},{"full_name":"Gardin, Andrea","first_name":"Andrea","last_name":"Gardin"},{"full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","last_name":"Klajn","first_name":"Rafal"},{"full_name":"Pavan, Giovanni M.","first_name":"Giovanni M.","last_name":"Pavan"}],"date_created":"2023-08-01T09:30:29Z","date_updated":"2023-08-02T06:51:15Z","volume":17,"extern":"1","publication":"ACS Nano","citation":{"short":"C. Lionello, C. Perego, A. Gardin, R. Klajn, G.M. Pavan, ACS Nano 17 (2023) 275–287.","mla":"Lionello, Chiara, et al. “Supramolecular Semiconductivity through Emerging Ionic Gates in Ion–Nanoparticle Superlattices.” ACS Nano, vol. 17, no. 1, American Chemical Society, 2023, pp. 275–87, doi:10.1021/acsnano.2c07558.","chicago":"Lionello, Chiara, Claudio Perego, Andrea Gardin, Rafal Klajn, and Giovanni M. Pavan. “Supramolecular Semiconductivity through Emerging Ionic Gates in Ion–Nanoparticle Superlattices.” ACS Nano. American Chemical Society, 2023. https://doi.org/10.1021/acsnano.2c07558.","ama":"Lionello C, Perego C, Gardin A, Klajn R, Pavan GM. Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices. ACS Nano. 2023;17(1):275-287. doi:10.1021/acsnano.2c07558","apa":"Lionello, C., Perego, C., Gardin, A., Klajn, R., & Pavan, G. M. (2023). Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices. ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.2c07558","ieee":"C. Lionello, C. Perego, A. Gardin, R. Klajn, and G. M. Pavan, “Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices,” ACS Nano, vol. 17, no. 1. American Chemical Society, pp. 275–287, 2023.","ista":"Lionello C, Perego C, Gardin A, Klajn R, Pavan GM. 2023. Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices. ACS Nano. 17(1), 275–287."},"article_type":"original","page":"275-287","date_published":"2023-01-10T00:00:00Z","scopus_import":"1","keyword":["General Physics and Astronomy","General Engineering","General Materials Science"],"day":"10","article_processing_charge":"No","_id":"13346","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","status":"public","title":"Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices","intvolume":" 17","oa_version":"Published Version","type":"journal_article","abstract":[{"text":"The self-assembly of nanoparticles driven by small molecules or ions may produce colloidal superlattices with features and properties reminiscent of those of metals or semiconductors. However, to what extent the properties of such supramolecular crystals actually resemble those of atomic materials often remains unclear. Here, we present coarse-grained molecular simulations explicitly demonstrating how a behavior evocative of that of semiconductors may emerge in a colloidal superlattice. As a case study, we focus on gold nanoparticles bearing positively charged groups that self-assemble into FCC crystals via mediation by citrate counterions. In silico ohmic experiments show how the dynamically diverse behavior of the ions in different superlattice domains allows the opening of conductive ionic gates above certain levels of applied electric fields. The observed binary conductive/nonconductive behavior is reminiscent of that of conventional semiconductors, while, at a supramolecular level, crossing the “band gap” requires a sufficient electrostatic stimulus to break the intermolecular interactions and make ions diffuse throughout the superlattice’s cavities.","lang":"eng"}],"issue":"1"},{"article_processing_charge":"No","day":"06","month":"07","doi":"10.48550/arXiv.2307.03237","date_published":"2023-07-06T00:00:00Z","language":[{"iso":"eng"}],"oa":1,"citation":{"ama":"Huber D, Pinsonneault M, Beck P, et al. Asteroseismology with the Roman galactic bulge time-domain survey. arXiv. doi:10.48550/arXiv.2307.03237","apa":"Huber, D., Pinsonneault, M., Beck, P., Bedding, T. R., Joss Bland-Hawthorn, J. B.-H., Breton, S. N., … Zinn, J. C. (n.d.). Asteroseismology with the Roman galactic bulge time-domain survey. arXiv. https://doi.org/10.48550/arXiv.2307.03237","ieee":"D. Huber et al., “Asteroseismology with the Roman galactic bulge time-domain survey,” arXiv. .","ista":"Huber D, Pinsonneault M, Beck P, Bedding TR, Joss Bland-Hawthorn JB-H, Breton SN, Bugnet LA, Chaplin WJ, Garcia RA, Grunblatt SK, Guzik JA, Hekker S, Kawaler SD, Mathis S, Mathur S, Metcalfe T, Mosser B, Ness MK, Piro AL, Serenelli A, Sharma S, Soderblom DR, Stassun KG, Stello D, Tayar J, Belle GT van, Zinn JC. Asteroseismology with the Roman galactic bulge time-domain survey. arXiv, 2307.03237.","short":"D. Huber, M. Pinsonneault, P. Beck, T.R. Bedding, J.B.-H. Joss Bland-Hawthorn, S.N. Breton, L.A. Bugnet, W.J. Chaplin, R.A. Garcia, S.K. Grunblatt, J.A. Guzik, S. Hekker, S.D. Kawaler, S. Mathis, S. Mathur, T. Metcalfe, B. Mosser, M.K. Ness, A.L. Piro, A. Serenelli, S. Sharma, D.R. Soderblom, K.G. Stassun, D. Stello, J. Tayar, G.T. van Belle, J.C. Zinn, ArXiv (n.d.).","mla":"Huber, Daniel, et al. “Asteroseismology with the Roman Galactic Bulge Time-Domain Survey.” ArXiv, 2307.03237, doi:10.48550/arXiv.2307.03237.","chicago":"Huber, Daniel, Marc Pinsonneault, Paul Beck, Timothy R. Bedding, Joss Bland-Hawthorn Joss Bland-Hawthorn, Sylvain N. Breton, Lisa Annabelle Bugnet, et al. “Asteroseismology with the Roman Galactic Bulge Time-Domain Survey.” ArXiv, n.d. https://doi.org/10.48550/arXiv.2307.03237."},"external_id":{"arxiv":["2307.03237"]},"main_file_link":[{"url":"https://doi.org/10.48550/arXiv.2307.03237","open_access":"1"}],"publication":"arXiv","abstract":[{"text":"Asteroseismology has transformed stellar astrophysics. Red giant asteroseismology is a prime example, with oscillation periods and amplitudes that are readily detectable with time-domain space-based telescopes. These oscillations can be used to infer masses, ages and radii for large numbers of stars, providing unique constraints on stellar populations in our galaxy. The cadence, duration, and spatial resolution of the Roman galactic bulge time-domain survey (GBTDS) are well-suited for asteroseismology and will probe an important population not studied by prior missions. We identify photometric precision as a key requirement for realizing the potential of asteroseismology with Roman. A precision of 1 mmag per 15-min cadence or better for saturated stars will enable detections of the populous red clump star population in the Galactic bulge. If the survey efficiency is better than expected, we argue for repeat observations of the same fields to improve photometric precision, or covering additional fields to expand the stellar population reach if the photometric precision for saturated stars is better than 1 mmag. Asteroseismology is relatively insensitive to the timing of the observations during the mission, and the prime red clump targets can be observed in a single 70 day campaign in any given field. Complementary stellar characterization, particularly astrometry tied to the Gaia system, will also dramatically expand the diagnostic power of asteroseismology. We also highlight synergies to Roman GBTDS exoplanet science using transits and microlensing.","lang":"eng"}],"type":"preprint","article_number":"2307.03237","author":[{"first_name":"Daniel","last_name":"Huber","full_name":"Huber, Daniel"},{"last_name":"Pinsonneault","first_name":"Marc","full_name":"Pinsonneault, Marc"},{"full_name":"Beck, Paul","first_name":"Paul","last_name":"Beck"},{"first_name":"Timothy R.","last_name":"Bedding","full_name":"Bedding, Timothy R."},{"full_name":"Joss Bland-Hawthorn, Joss Bland-Hawthorn","first_name":"Joss Bland-Hawthorn","last_name":"Joss Bland-Hawthorn"},{"last_name":"Breton","first_name":"Sylvain N.","full_name":"Breton, Sylvain N."},{"orcid":"0000-0003-0142-4000","id":"d9edb345-f866-11ec-9b37-d119b5234501","last_name":"Bugnet","first_name":"Lisa Annabelle","full_name":"Bugnet, Lisa Annabelle"},{"last_name":"Chaplin","first_name":"William J.","full_name":"Chaplin, William J."},{"last_name":"Garcia","first_name":"Rafael A.","full_name":"Garcia, Rafael A."},{"last_name":"Grunblatt","first_name":"Samuel K.","full_name":"Grunblatt, Samuel K."},{"full_name":"Guzik, Joyce A.","first_name":"Joyce A.","last_name":"Guzik"},{"full_name":"Hekker, Saskia","first_name":"Saskia","last_name":"Hekker"},{"full_name":"Kawaler, Steven D.","first_name":"Steven D.","last_name":"Kawaler"},{"last_name":"Mathis","first_name":"Stephane","full_name":"Mathis, Stephane"},{"first_name":"Savita","last_name":"Mathur","full_name":"Mathur, Savita"},{"last_name":"Metcalfe","first_name":"Travis","full_name":"Metcalfe, Travis"},{"full_name":"Mosser, Benoit","first_name":"Benoit","last_name":"Mosser"},{"first_name":"Melissa K.","last_name":"Ness","full_name":"Ness, Melissa K."},{"full_name":"Piro, Anthony L.","last_name":"Piro","first_name":"Anthony L."},{"full_name":"Serenelli, Aldo","last_name":"Serenelli","first_name":"Aldo"},{"first_name":"Sanjib","last_name":"Sharma","full_name":"Sharma, Sanjib"},{"full_name":"Soderblom, David R.","first_name":"David R.","last_name":"Soderblom"},{"last_name":"Stassun","first_name":"Keivan G.","full_name":"Stassun, Keivan G."},{"last_name":"Stello","first_name":"Dennis","full_name":"Stello, Dennis"},{"last_name":"Tayar","first_name":"Jamie","full_name":"Tayar, Jamie"},{"first_name":"Gerard T. van","last_name":"Belle","full_name":"Belle, Gerard T. van"},{"full_name":"Zinn, Joel C.","last_name":"Zinn","first_name":"Joel C."}],"oa_version":"Preprint","date_updated":"2023-08-02T07:36:00Z","date_created":"2023-08-02T07:30:43Z","_id":"13447","year":"2023","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","department":[{"_id":"LiBu"}],"publication_status":"submitted","title":"Asteroseismology with the Roman galactic bulge time-domain survey","status":"public"},{"month":"02","publication_identifier":{"eissn":["1520-5126"],"issn":["0002-7863"]},"main_file_link":[{"url":"https://doi.org/10.1021/jacs.2c11973","open_access":"1"}],"external_id":{"pmid":["36757850"]},"oa":1,"quality_controlled":"1","doi":"10.1021/jacs.2c11973","language":[{"iso":"eng"}],"extern":"1","year":"2023","pmid":1,"publication_status":"published","publisher":"American Chemical Society","author":[{"last_name":"Wang","first_name":"Jinhua","full_name":"Wang, Jinhua"},{"last_name":"Peled","first_name":"Tzuf Shay","full_name":"Peled, Tzuf Shay"},{"full_name":"Klajn, Rafal","first_name":"Rafal","last_name":"Klajn","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"}],"date_updated":"2023-08-02T10:44:22Z","date_created":"2023-08-01T09:33:08Z","volume":145,"scopus_import":"1","keyword":["Colloid and Surface Chemistry","Biochemistry","General Chemistry","Catalysis"],"day":"09","article_processing_charge":"No","publication":"Journal of the American Chemical Society","citation":{"ama":"Wang J, Peled TS, Klajn R. Photocleavable anionic glues for light-responsive nanoparticle aggregates. Journal of the American Chemical Society. 2023;145(7):4098-4108. doi:10.1021/jacs.2c11973","ieee":"J. Wang, T. S. Peled, and R. Klajn, “Photocleavable anionic glues for light-responsive nanoparticle aggregates,” Journal of the American Chemical Society, vol. 145, no. 7. American Chemical Society, pp. 4098–4108, 2023.","apa":"Wang, J., Peled, T. S., & Klajn, R. (2023). Photocleavable anionic glues for light-responsive nanoparticle aggregates. Journal of the American Chemical Society. American Chemical Society. https://doi.org/10.1021/jacs.2c11973","ista":"Wang J, Peled TS, Klajn R. 2023. Photocleavable anionic glues for light-responsive nanoparticle aggregates. Journal of the American Chemical Society. 145(7), 4098–4108.","short":"J. Wang, T.S. Peled, R. Klajn, Journal of the American Chemical Society 145 (2023) 4098–4108.","mla":"Wang, Jinhua, et al. “Photocleavable Anionic Glues for Light-Responsive Nanoparticle Aggregates.” Journal of the American Chemical Society, vol. 145, no. 7, American Chemical Society, 2023, pp. 4098–108, doi:10.1021/jacs.2c11973.","chicago":"Wang, Jinhua, Tzuf Shay Peled, and Rafal Klajn. “Photocleavable Anionic Glues for Light-Responsive Nanoparticle Aggregates.” Journal of the American Chemical Society. American Chemical Society, 2023. https://doi.org/10.1021/jacs.2c11973."},"article_type":"original","page":"4098-4108","date_published":"2023-02-09T00:00:00Z","type":"journal_article","abstract":[{"lang":"eng","text":"Integrating light-sensitive molecules within nanoparticle (NP) assemblies is an attractive approach to fabricate new photoresponsive nanomaterials. Here, we describe the concept of photocleavable anionic glue (PAG): small trianions capable of mediating interactions between (and inducing the aggregation of) cationic NPs by means of electrostatic interactions. Exposure to light converts PAGs into dianionic products incapable of maintaining the NPs in an assembled state, resulting in light-triggered disassembly of NP aggregates. To demonstrate the proof-of-concept, we work with an organic PAG incorporating the UV-cleavable o-nitrobenzyl moiety and an inorganic PAG, the photosensitive trioxalatocobaltate(III) complex, which absorbs light across the entire visible spectrum. Both PAGs were used to prepare either amorphous NP assemblies or regular superlattices with a long-range NP order. These NP aggregates disassembled rapidly upon light exposure for a specific time, which could be tuned by the incident light wavelength or the amount of PAG used. Selective excitation of the inorganic PAG in a system combining the two PAGs results in a photodecomposition product that deactivates the organic PAG, enabling nontrivial disassembly profiles under a single type of external stimulus."}],"issue":"7","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","_id":"13354","status":"public","title":"Photocleavable anionic glues for light-responsive nanoparticle aggregates","intvolume":" 145","oa_version":"Published Version"}]