[{"article_number":"e2022MS003391","title":"A shallow‐deep unified stochastic mass flux cumulus parameterization in the single column community climate model","author":[{"first_name":"B.","full_name":"Khouider, B.","last_name":"Khouider"},{"id":"3a4ac09c-6d61-11ec-bf66-884cde66b64b","first_name":"BIDYUT B","full_name":"GOSWAMI, BIDYUT B","orcid":"0000-0001-8602-3083","last_name":"GOSWAMI"},{"first_name":"R.","full_name":"Phani, R.","last_name":"Phani"},{"last_name":"Majda","full_name":"Majda, A. J.","first_name":"A. J."}],"article_processing_charge":"Yes","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","citation":{"chicago":"Khouider, B., BIDYUT B GOSWAMI, R. Phani, and A. J. Majda. “A Shallow‐deep Unified Stochastic Mass Flux Cumulus Parameterization in the Single Column Community Climate Model.” Journal of Advances in Modeling Earth Systems. American Geophysical Union, 2023. https://doi.org/10.1029/2022ms003391.","ista":"Khouider B, GOSWAMI BB, Phani R, Majda AJ. 2023. A shallow‐deep unified stochastic mass flux cumulus parameterization in the single column community climate model. Journal of Advances in Modeling Earth Systems. 15(11), e2022MS003391.","mla":"Khouider, B., et al. “A Shallow‐deep Unified Stochastic Mass Flux Cumulus Parameterization in the Single Column Community Climate Model.” Journal of Advances in Modeling Earth Systems, vol. 15, no. 11, e2022MS003391, American Geophysical Union, 2023, doi:10.1029/2022ms003391.","short":"B. Khouider, B.B. GOSWAMI, R. Phani, A.J. Majda, Journal of Advances in Modeling Earth Systems 15 (2023).","ieee":"B. Khouider, B. B. GOSWAMI, R. Phani, and A. J. Majda, “A shallow‐deep unified stochastic mass flux cumulus parameterization in the single column community climate model,” Journal of Advances in Modeling Earth Systems, vol. 15, no. 11. American Geophysical Union, 2023.","apa":"Khouider, B., GOSWAMI, B. B., Phani, R., & Majda, A. J. (2023). A shallow‐deep unified stochastic mass flux cumulus parameterization in the single column community climate model. Journal of Advances in Modeling Earth Systems. American Geophysical Union. https://doi.org/10.1029/2022ms003391","ama":"Khouider B, GOSWAMI BB, Phani R, Majda AJ. A shallow‐deep unified stochastic mass flux cumulus parameterization in the single column community climate model. Journal of Advances in Modeling Earth Systems. 2023;15(11). doi:10.1029/2022ms003391"},"publisher":"American Geophysical Union","quality_controlled":"1","oa":1,"acknowledgement":"The research of B.K. is supported in part by a Discovery Grant from the Natural Sciences and Engineering Research Council of Canada (RGPIN-04246-2020). This research was conducted during the visits of P.M. Krishna to the Center for Prototype Climate Models at NYU Abu Dhabi and University of Victoria from November 2018 to June 2019 and July 2019 and October 2019, respectively. The authors are very grateful to the three anonymous reviewers who provided very thoughtful and constructive comments during the review process that helped greatly improve and shape the final version of the manuscript.","date_published":"2023-11-01T00:00:00Z","doi":"10.1029/2022ms003391","date_created":"2023-11-20T09:18:21Z","day":"01","publication":"Journal of Advances in Modeling Earth Systems","has_accepted_license":"1","year":"2023","status":"public","keyword":["General Earth and Planetary Sciences","Environmental Chemistry","Global and Planetary Change"],"article_type":"original","type":"journal_article","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by-nc/4.0/legalcode","image":"/images/cc_by_nc.png","name":"Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)","short":"CC BY-NC (4.0)"},"_id":"14564","department":[{"_id":"CaMu"}],"file_date_updated":"2023-11-20T11:29:16Z","ddc":["550"],"date_updated":"2023-11-28T12:04:42Z","month":"11","intvolume":" 15","scopus_import":"1","oa_version":"Published Version","abstract":[{"lang":"eng","text":"Cumulus parameterization (CP) in state‐of‐the‐art global climate models is based on the quasi‐equilibrium assumption (QEA), which views convection as the action of an ensemble of cumulus clouds, in a state of equilibrium with respect to a slowly varying atmospheric state. This view is not compatible with the organization and dynamical interactions across multiple scales of cloud systems in the tropics and progress in this research area was slow over decades despite the widely recognized major shortcomings. Novel ideas on how to represent key physical processes of moist convection‐large‐scale interaction to overcome the QEA have surged recently. The stochastic multicloud model (SMCM) CP in particular mimics the dynamical interactions of multiple cloud types that characterize organized tropical convection. Here, the SMCM is used to modify the Zhang‐McFarlane (ZM) CP by changing the way in which the bulk mass flux and bulk entrainment and detrainment rates are calculated. This is done by introducing a stochastic ensemble of plumes characterized by randomly varying detrainment level distributions based on the cloud area fraction of the SMCM. The SMCM is here extended to include shallow cumulus clouds resulting in a unified shallow‐deep CP. The new stochastic multicloud plume CP is validated against the control ZM scheme in the context of the single column Community Climate Model of the National Center for Atmospheric Research using data from both tropical ocean and midlatitude land convection. Some key features of the SMCM CP such as it capability to represent the tri‐modal nature of organized convection are emphasized."}],"issue":"11","volume":15,"license":"https://creativecommons.org/licenses/by-nc/4.0/","file":[{"creator":"dernst","date_updated":"2023-11-20T11:29:16Z","file_size":6435697,"date_created":"2023-11-20T11:29:16Z","file_name":"2023_JAMES_Khoulder.pdf","access_level":"open_access","relation":"main_file","content_type":"application/pdf","checksum":"e30329dd985559de0ddc7021ca7382b4","file_id":"14582","success":1}],"language":[{"iso":"eng"}],"publication_identifier":{"eissn":["1942-2466"]},"publication_status":"published"},{"_id":"14786","type":"journal_article","article_type":"original","keyword":["Pollution","Waste Management and Disposal","Environmental Chemistry","Environmental Engineering"],"status":"public","date_updated":"2024-01-16T10:04:57Z","department":[{"_id":"LifeSc"}],"abstract":[{"text":"Acanthocephalans, intestinal parasites of vertebrates, are characterised by orders of magnitude higher metal accumulation than free-living organisms, but the mechanism of such effective metal accumulation is still unknown. The aim of our study was to gain new insights into the high-resolution localization of elements in the bodies of acanthocephalans, thus taking an initial step towards elucidating metal uptake and accumulation in organisms under real environmental conditions. For the first time, nanoscale secondary ion mass spectrometry (NanoSIMS) was used for high-resolution mapping of 12 elements (C, Ca, Cu, Fe, N, Na, O, P, Pb, S, Se, and Tl) in three selected body parts (trunk spines, inner part of the proboscis receptacle and inner surface of the tegument) of Dentitruncus truttae, a parasite of brown trout (Salmo trutta) from the Krka River in Croatia. In addition, the same body parts were examined using transmission electron microscopy (TEM) and correlated with NanoSIMS images. Metal concentrations determined using HR ICP-MS confirmed higher accumulation in D. truttae than in the fish intestine. The chemical composition of the acanthocephalan body showed the highest density of C, Ca, N, Na, O, S, as important and constitutive elements in living cells in all studied structures, while Fe was predominant among trace elements. In general, higher element density was found in trunk spines and tegument, as body structures responsible for substance absorption in parasites. The results obtained with NanoSIMS and TEM-NanoSIMS correlative imaging represent pilot data for mapping of elements at nanoscale resolution in the ultrastructure of various body parts of acanthocephalans and generally provide a contribution for further application of this technique in all parasite species.","lang":"eng"}],"pmid":1,"oa_version":"None","intvolume":" 887","month":"08","publication_status":"published","publication_identifier":{"issn":["0048-9697"]},"language":[{"iso":"eng"}],"volume":887,"article_number":"164010","citation":{"mla":"Filipović Marijić, Vlatka, et al. “First Insight in Element Localisation in Different Body Parts of the Acanthocephalan Dentitruncus Truttae Using TEM and NanoSIMS.” Science of The Total Environment, vol. 887, 164010, Elsevier, 2023, doi:10.1016/j.scitotenv.2023.164010.","ieee":"V. Filipović Marijić et al., “First insight in element localisation in different body parts of the acanthocephalan Dentitruncus truttae using TEM and NanoSIMS,” Science of The Total Environment, vol. 887. Elsevier, 2023.","short":"V. Filipović Marijić, M.A. Subirana, D. Schaumlöffel, J. Barišić, E. Gontier, N. Krasnici, T. Mijošek, J.S. Hernández-Orts, T. Scholz, M. Erk, Science of The Total Environment 887 (2023).","apa":"Filipović Marijić, V., Subirana, M. A., Schaumlöffel, D., Barišić, J., Gontier, E., Krasnici, N., … Erk, M. (2023). First insight in element localisation in different body parts of the acanthocephalan Dentitruncus truttae using TEM and NanoSIMS. Science of The Total Environment. Elsevier. https://doi.org/10.1016/j.scitotenv.2023.164010","ama":"Filipović Marijić V, Subirana MA, Schaumlöffel D, et al. First insight in element localisation in different body parts of the acanthocephalan Dentitruncus truttae using TEM and NanoSIMS. Science of The Total Environment. 2023;887. doi:10.1016/j.scitotenv.2023.164010","chicago":"Filipović Marijić, Vlatka, Maria Angels Subirana, Dirk Schaumlöffel, Josip Barišić, Etienne Gontier, Nesrete Krasnici, Tatjana Mijošek, Jesús S. Hernández-Orts, Tomáš Scholz, and Marijana Erk. “First Insight in Element Localisation in Different Body Parts of the Acanthocephalan Dentitruncus Truttae Using TEM and NanoSIMS.” Science of The Total Environment. Elsevier, 2023. https://doi.org/10.1016/j.scitotenv.2023.164010.","ista":"Filipović Marijić V, Subirana MA, Schaumlöffel D, Barišić J, Gontier E, Krasnici N, Mijošek T, Hernández-Orts JS, Scholz T, Erk M. 2023. First insight in element localisation in different body parts of the acanthocephalan Dentitruncus truttae using TEM and NanoSIMS. Science of The Total Environment. 887, 164010."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","external_id":{"isi":["001002645100001"],"pmid":["37169189"]},"article_processing_charge":"No","author":[{"first_name":"Vlatka","full_name":"Filipović Marijić, Vlatka","last_name":"Filipović Marijić"},{"full_name":"Subirana, Maria Angels","last_name":"Subirana","first_name":"Maria Angels"},{"last_name":"Schaumlöffel","full_name":"Schaumlöffel, Dirk","first_name":"Dirk"},{"first_name":"Josip","last_name":"Barišić","full_name":"Barišić, Josip"},{"full_name":"Gontier, Etienne","last_name":"Gontier","first_name":"Etienne"},{"full_name":"Krasnici, Nesrete","last_name":"Krasnici","id":"cb5852d4-287f-11ed-baf0-bc1dd2d5c745","first_name":"Nesrete"},{"first_name":"Tatjana","full_name":"Mijošek, Tatjana","last_name":"Mijošek"},{"first_name":"Jesús S.","full_name":"Hernández-Orts, Jesús S.","last_name":"Hernández-Orts"},{"last_name":"Scholz","full_name":"Scholz, Tomáš","first_name":"Tomáš"},{"full_name":"Erk, Marijana","last_name":"Erk","first_name":"Marijana"}],"title":"First insight in element localisation in different body parts of the acanthocephalan Dentitruncus truttae using TEM and NanoSIMS","acknowledgement":"The authors thank the Czech Science Foundation (project No. 19-28399X) and the Czech Academy of Sciences (RVO: 60077344) and are sincerely grateful to the Bordeaux Imaging Centre (member of the France BioImaging national infrastructure, ANR-10-INBS-04) for help with TEM and to members of the Laboratory of Biological Effects of Metals and Laboratory of Aquaculture and Pathology of Aquatic Organisms (Ruđer Bošković Institute, Croatia) for the assistance with fieldwork.","publisher":"Elsevier","quality_controlled":"1","year":"2023","isi":1,"publication":"Science of The Total Environment","day":"20","date_created":"2024-01-10T10:43:08Z","doi":"10.1016/j.scitotenv.2023.164010","date_published":"2023-08-20T00:00:00Z"},{"title":"Encapsulation within a coordination cage modulates the reactivity of redox-active dyes","author":[{"first_name":"Oksana","full_name":"Yanshyna, Oksana","last_name":"Yanshyna"},{"first_name":"Michał J.","last_name":"Białek","full_name":"Białek, Michał J."},{"first_name":"Oleg V.","last_name":"Chashchikhin","full_name":"Chashchikhin, Oleg V."},{"last_name":"Klajn","full_name":"Klajn, Rafal","first_name":"Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"}],"article_processing_charge":"No","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","citation":{"mla":"Yanshyna, Oksana, et al. “Encapsulation within a Coordination Cage Modulates the Reactivity of Redox-Active Dyes.” Communications Chemistry, vol. 5, 44, Springer Nature, 2022, doi:10.1038/s42004-022-00658-8.","ieee":"O. Yanshyna, M. J. Białek, O. V. Chashchikhin, and R. Klajn, “Encapsulation within a coordination cage modulates the reactivity of redox-active dyes,” Communications Chemistry, vol. 5. Springer Nature, 2022.","short":"O. Yanshyna, M.J. Białek, O.V. Chashchikhin, R. Klajn, Communications Chemistry 5 (2022).","ama":"Yanshyna O, Białek MJ, Chashchikhin OV, Klajn R. Encapsulation within a coordination cage modulates the reactivity of redox-active dyes. Communications Chemistry. 2022;5. doi:10.1038/s42004-022-00658-8","apa":"Yanshyna, O., Białek, M. J., Chashchikhin, O. V., & Klajn, R. (2022). Encapsulation within a coordination cage modulates the reactivity of redox-active dyes. Communications Chemistry. Springer Nature. https://doi.org/10.1038/s42004-022-00658-8","chicago":"Yanshyna, Oksana, Michał J. Białek, Oleg V. Chashchikhin, and Rafal Klajn. “Encapsulation within a Coordination Cage Modulates the Reactivity of Redox-Active Dyes.” Communications Chemistry. Springer Nature, 2022. https://doi.org/10.1038/s42004-022-00658-8.","ista":"Yanshyna O, Białek MJ, Chashchikhin OV, Klajn R. 2022. Encapsulation within a coordination cage modulates the reactivity of redox-active dyes. Communications Chemistry. 5, 44."},"article_number":"44","doi":"10.1038/s42004-022-00658-8","date_published":"2022-03-30T00:00:00Z","date_created":"2023-08-01T09:30:47Z","day":"30","publication":"Communications Chemistry","year":"2022","quality_controlled":"1","publisher":"Springer Nature","oa":1,"extern":"1","date_updated":"2023-08-02T06:41:54Z","status":"public","keyword":["Materials Chemistry","Biochemistry","Environmental Chemistry","General Chemistry"],"article_type":"original","type":"journal_article","_id":"13347","volume":5,"language":[{"iso":"eng"}],"publication_identifier":{"eissn":["2399-3669"]},"publication_status":"published","month":"03","intvolume":" 5","scopus_import":"1","main_file_link":[{"url":"https://doi.org/10.1038/s42004-022-00658-8","open_access":"1"}],"oa_version":"Published Version","abstract":[{"text":"Confining molecules within well-defined nanosized spaces can profoundly alter their physicochemical characteristics. For example, the controlled aggregation of chromophores into discrete oligomers has been shown to tune their optical properties whereas encapsulation of reactive species within molecular hosts can increase their stability. The resazurin/resorufin pair has been widely used for detecting redox processes in biological settings; yet, how tight confinement affects the properties of these two dyes remains to be explored. Here, we show that a flexible PdII6L4 coordination cage can efficiently encapsulate both resorufin and resazurin in the form of dimers, dramatically modulating their optical properties. Furthermore, binding within the cage significantly decreases the reduction rate of resazurin to resorufin, and the rate of the subsequent reduction of resorufin to dihydroresorufin. During our studies, we also found that upon dilution, the PdII6L4 cage disassembles to afford PdII2L2 species, which lacks the ability to form inclusion complexes – a process that can be reversed upon the addition of the strongly binding resorufin/resazurin guests. We expect that the herein disclosed ability of a water-soluble cage to reversibly modulate the optical and chemical properties of a molecular redox probe will expand the versatility of synthetic fluorescent probes in biologically relevant environments.","lang":"eng"}]},{"date_created":"2023-08-01T09:32:27Z","date_published":"2022-05-12T00:00:00Z","doi":"10.1016/j.chempr.2022.04.022","page":"1183-1186","publication":"Chem","day":"12","year":"2022","oa":1,"quality_controlled":"1","publisher":"Elsevier","title":"Electron catalysis expands the supramolecular chemist’s toolbox","article_processing_charge":"No","author":[{"first_name":"Julius","full_name":"Gemen, Julius","last_name":"Gemen"},{"full_name":"Klajn, Rafal","last_name":"Klajn","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","first_name":"Rafal"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","citation":{"ista":"Gemen J, Klajn R. 2022. Electron catalysis expands the supramolecular chemist’s toolbox. Chem. 8(5), 1183–1186.","chicago":"Gemen, Julius, and Rafal Klajn. “Electron Catalysis Expands the Supramolecular Chemist’s Toolbox.” Chem. Elsevier, 2022. https://doi.org/10.1016/j.chempr.2022.04.022.","short":"J. Gemen, R. Klajn, Chem 8 (2022) 1183–1186.","ieee":"J. Gemen and R. Klajn, “Electron catalysis expands the supramolecular chemist’s toolbox,” Chem, vol. 8, no. 5. Elsevier, pp. 1183–1186, 2022.","ama":"Gemen J, Klajn R. Electron catalysis expands the supramolecular chemist’s toolbox. Chem. 2022;8(5):1183-1186. doi:10.1016/j.chempr.2022.04.022","apa":"Gemen, J., & Klajn, R. (2022). Electron catalysis expands the supramolecular chemist’s toolbox. Chem. Elsevier. https://doi.org/10.1016/j.chempr.2022.04.022","mla":"Gemen, Julius, and Rafal Klajn. “Electron Catalysis Expands the Supramolecular Chemist’s Toolbox.” Chem, vol. 8, no. 5, Elsevier, 2022, pp. 1183–86, doi:10.1016/j.chempr.2022.04.022."},"issue":"5","volume":8,"language":[{"iso":"eng"}],"publication_status":"published","publication_identifier":{"eissn":["2451-9294"],"issn":["2451-9308"]},"intvolume":" 8","month":"05","main_file_link":[{"url":"https://doi.org/10.1016/j.chempr.2022.04.022","open_access":"1"}],"scopus_import":"1","oa_version":"Published Version","abstract":[{"text":"Molecular recognition is at the heart of the noncovalent synthesis of supramolecular assemblies and, at higher length scales, supramolecular materials. In a recent publication in Nature, Stoddart and co-workers demonstrate that the formation of host-guest complexes can be catalyzed by one of the simplest possible catalysts: the electron.","lang":"eng"}],"extern":"1","date_updated":"2023-08-02T07:24:57Z","keyword":["Materials Chemistry","Biochemistry (medical)","General Chemical Engineering","Environmental Chemistry","Biochemistry","General Chemistry"],"status":"public","type":"journal_article","article_type":"original","_id":"13351"},{"citation":{"ista":"Gemen J, Białek MJ, Kazes M, Shimon LJW, Feller M, Semenov SN, Diskin-Posner Y, Oron D, Klajn R. 2022. Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence. Chem. 8(9), 2362–2379.","chicago":"Gemen, Julius, Michał J. Białek, Miri Kazes, Linda J.W. Shimon, Moran Feller, Sergey N. Semenov, Yael Diskin-Posner, Dan Oron, and Rafal Klajn. “Ternary Host-Guest Complexes with Rapid Exchange Kinetics and Photoswitchable Fluorescence.” Chem. Elsevier, 2022. https://doi.org/10.1016/j.chempr.2022.05.008.","ama":"Gemen J, Białek MJ, Kazes M, et al. Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence. Chem. 2022;8(9):2362-2379. doi:10.1016/j.chempr.2022.05.008","apa":"Gemen, J., Białek, M. J., Kazes, M., Shimon, L. J. W., Feller, M., Semenov, S. N., … Klajn, R. (2022). Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence. Chem. Elsevier. https://doi.org/10.1016/j.chempr.2022.05.008","short":"J. Gemen, M.J. Białek, M. Kazes, L.J.W. Shimon, M. Feller, S.N. Semenov, Y. Diskin-Posner, D. Oron, R. Klajn, Chem 8 (2022) 2362–2379.","ieee":"J. Gemen et al., “Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence,” Chem, vol. 8, no. 9. Elsevier, pp. 2362–2379, 2022.","mla":"Gemen, Julius, et al. “Ternary Host-Guest Complexes with Rapid Exchange Kinetics and Photoswitchable Fluorescence.” Chem, vol. 8, no. 9, Elsevier, 2022, pp. 2362–79, doi:10.1016/j.chempr.2022.05.008."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","article_processing_charge":"No","external_id":{"pmid":["36133801"]},"author":[{"full_name":"Gemen, Julius","last_name":"Gemen","first_name":"Julius"},{"first_name":"Michał J.","last_name":"Białek","full_name":"Białek, Michał J."},{"first_name":"Miri","last_name":"Kazes","full_name":"Kazes, Miri"},{"first_name":"Linda J.W.","last_name":"Shimon","full_name":"Shimon, Linda J.W."},{"first_name":"Moran","last_name":"Feller","full_name":"Feller, Moran"},{"first_name":"Sergey N.","last_name":"Semenov","full_name":"Semenov, Sergey N."},{"first_name":"Yael","last_name":"Diskin-Posner","full_name":"Diskin-Posner, Yael"},{"full_name":"Oron, Dan","last_name":"Oron","first_name":"Dan"},{"first_name":"Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","last_name":"Klajn","full_name":"Klajn, Rafal"}],"title":"Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence","oa":1,"quality_controlled":"1","publisher":"Elsevier","year":"2022","publication":"Chem","day":"08","page":"2362-2379","date_created":"2023-08-01T09:32:14Z","date_published":"2022-09-08T00:00:00Z","doi":"10.1016/j.chempr.2022.05.008","_id":"13350","type":"journal_article","article_type":"original","keyword":["Materials Chemistry","Biochemistry (medical)","General Chemical Engineering","Environmental Chemistry","Biochemistry","General Chemistry"],"status":"public","date_updated":"2023-08-02T09:39:35Z","extern":"1","abstract":[{"lang":"eng","text":"Confinement within molecular cages can dramatically modify the physicochemical properties of the encapsulated guest molecules, but such host-guest complexes have mainly been studied in a static context. Combining confinement effects with fast guest exchange kinetics could pave the way toward stimuli-responsive supramolecular systems—and ultimately materials—whose desired properties could be tailored “on demand” rapidly and reversibly. Here, we demonstrate rapid guest exchange between inclusion complexes of an open-window coordination cage that can simultaneously accommodate two guest molecules. Working with two types of guests, anthracene derivatives and BODIPY dyes, we show that the former can substantially modify the optical properties of the latter upon noncovalent heterodimer formation. We also studied the light-induced covalent dimerization of encapsulated anthracenes and found large effects of confinement on reaction rates. By coupling the photodimerization with the rapid guest exchange, we developed a new way to modulate fluorescence using external irradiation."}],"oa_version":"Published Version","pmid":1,"main_file_link":[{"url":"https://doi.org/10.1016/j.chempr.2022.05.008","open_access":"1"}],"scopus_import":"1","intvolume":" 8","month":"09","publication_status":"published","publication_identifier":{"issn":["2451-9308"],"eissn":["2451-9294"]},"language":[{"iso":"eng"}],"issue":"9","volume":8},{"department":[{"_id":"MaIb"}],"date_updated":"2024-01-22T08:13:43Z","article_type":"original","type":"journal_article","status":"public","keyword":["Pollution","Nuclear Energy and Engineering","Renewable Energy","Sustainability and the Environment","Environmental Chemistry"],"_id":"12155","related_material":{"link":[{"url":"https://doi.org/10.1039/d3ee90067c","relation":"erratum"}]},"issue":"11","volume":15,"publication_identifier":{"issn":["1754-5692"],"eissn":["1754-5706"]},"publication_status":"published","language":[{"iso":"eng"}],"scopus_import":"1","month":"11","intvolume":" 15","abstract":[{"lang":"eng","text":"The growing demand of thermal management in various fields such as miniaturized 5G chips has motivated researchers to develop new and high-performance solid-state refrigeration technologies, typically including multicaloric and thermoelectric (TE) cooling. Among them, TE cooling has attracted huge attention owing to its advantages of rapid response, large cooling temperature difference, high stability, and tunable device size. Bi2Te3-based alloys have long been the only commercialized TE cooling materials, while novel systems SnSe and Mg3(Bi,Sb)2 have recently been discovered as potential candidates. However, challenges and problems still require to be summarized and further resolved for realizing better cooling performance. In this review, we systematically investigate TE cooling from its internal mechanism, crucial parameters, to device design and applications. Furthermore, we summarize the current optimization strategies for existing TE cooling materials, and finally provide some personal prospects especially the material-planification concept on future research on establishing better TE cooling."}],"oa_version":"None","author":[{"first_name":"Yongxin","full_name":"Qin, Yongxin","last_name":"Qin"},{"first_name":"Bingchao","full_name":"Qin, Bingchao","last_name":"Qin"},{"last_name":"Wang","full_name":"Wang, Dongyang","first_name":"Dongyang"},{"last_name":"Chang","orcid":"0000-0002-9515-4277","full_name":"Chang, Cheng","first_name":"Cheng","id":"9E331C2E-9F27-11E9-AE48-5033E6697425"},{"first_name":"Li-Dong","full_name":"Zhao, Li-Dong","last_name":"Zhao"}],"external_id":{"isi":["000863642400001"]},"article_processing_charge":"No","title":"Solid-state cooling: Thermoelectrics","citation":{"ama":"Qin Y, Qin B, Wang D, Chang C, Zhao L-D. Solid-state cooling: Thermoelectrics. Energy & Environmental Science. 2022;15(11):4527-4541. doi:10.1039/d2ee02408j","apa":"Qin, Y., Qin, B., Wang, D., Chang, C., & Zhao, L.-D. (2022). Solid-state cooling: Thermoelectrics. Energy & Environmental Science. Royal Society of Chemistry. https://doi.org/10.1039/d2ee02408j","short":"Y. Qin, B. Qin, D. Wang, C. Chang, L.-D. Zhao, Energy & Environmental Science 15 (2022) 4527–4541.","ieee":"Y. Qin, B. Qin, D. Wang, C. Chang, and L.-D. Zhao, “Solid-state cooling: Thermoelectrics,” Energy & Environmental Science, vol. 15, no. 11. Royal Society of Chemistry, pp. 4527–4541, 2022.","mla":"Qin, Yongxin, et al. “Solid-State Cooling: Thermoelectrics.” Energy & Environmental Science, vol. 15, no. 11, Royal Society of Chemistry, 2022, pp. 4527–41, doi:10.1039/d2ee02408j.","ista":"Qin Y, Qin B, Wang D, Chang C, Zhao L-D. 2022. Solid-state cooling: Thermoelectrics. Energy & Environmental Science. 15(11), 4527–4541.","chicago":"Qin, Yongxin, Bingchao Qin, Dongyang Wang, Cheng Chang, and Li-Dong Zhao. “Solid-State Cooling: Thermoelectrics.” Energy & Environmental Science. Royal Society of Chemistry, 2022. https://doi.org/10.1039/d2ee02408j."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","page":"4527-4541","date_published":"2022-11-01T00:00:00Z","doi":"10.1039/d2ee02408j","date_created":"2023-01-12T12:08:41Z","isi":1,"year":"2022","day":"01","publication":"Energy & Environmental Science","publisher":"Royal Society of Chemistry","quality_controlled":"1","acknowledgement":"We acknowledge support from the National Key Research and Development Program of China (2018YFA0702100), the National Natural Science Foundation of China (51571007, 51772012, 52002011 and 52002042), the Basic Science Center Project of National Natural Science Foundation of China (51788104), Beijing Natural Science Foundation (JQ18004), 111 Project (B17002), and the National Science Fund for Distinguished Young Scholars (51925101)."},{"article_number":"e2020MS002256","title":"Distortions of the rain distribution with warming, with and without self‐aggregation","article_processing_charge":"No","author":[{"first_name":"Benjamin","full_name":"Fildier, Benjamin","last_name":"Fildier"},{"first_name":"William D.","last_name":"Collins","full_name":"Collins, William D."},{"last_name":"Muller","full_name":"Muller, Caroline J","orcid":"0000-0001-5836-5350","id":"f978ccb0-3f7f-11eb-b193-b0e2bd13182b","first_name":"Caroline J"}],"user_id":"8b945eb4-e2f2-11eb-945a-df72226e66a9","citation":{"mla":"Fildier, Benjamin, et al. “Distortions of the Rain Distribution with Warming, with and without Self‐aggregation.” Journal of Advances in Modeling Earth Systems, vol. 13, no. 2, e2020MS002256, American Geophysical Union, 2021, doi:10.1029/2020ms002256.","apa":"Fildier, B., Collins, W. D., & Muller, C. J. (2021). Distortions of the rain distribution with warming, with and without self‐aggregation. Journal of Advances in Modeling Earth Systems. American Geophysical Union. https://doi.org/10.1029/2020ms002256","ama":"Fildier B, Collins WD, Muller CJ. Distortions of the rain distribution with warming, with and without self‐aggregation. Journal of Advances in Modeling Earth Systems. 2021;13(2). doi:10.1029/2020ms002256","short":"B. Fildier, W.D. Collins, C.J. Muller, Journal of Advances in Modeling Earth Systems 13 (2021).","ieee":"B. Fildier, W. D. Collins, and C. J. Muller, “Distortions of the rain distribution with warming, with and without self‐aggregation,” Journal of Advances in Modeling Earth Systems, vol. 13, no. 2. American Geophysical Union, 2021.","chicago":"Fildier, Benjamin, William D. Collins, and Caroline J Muller. “Distortions of the Rain Distribution with Warming, with and without Self‐aggregation.” Journal of Advances in Modeling Earth Systems. American Geophysical Union, 2021. https://doi.org/10.1029/2020ms002256.","ista":"Fildier B, Collins WD, Muller CJ. 2021. Distortions of the rain distribution with warming, with and without self‐aggregation. Journal of Advances in Modeling Earth Systems. 13(2), e2020MS002256."},"oa":1,"quality_controlled":"1","publisher":"American Geophysical Union","date_created":"2021-02-15T15:10:01Z","doi":"10.1029/2020ms002256","date_published":"2021-02-01T00:00:00Z","publication":"Journal of Advances in Modeling Earth Systems","day":"01","year":"2021","has_accepted_license":"1","keyword":["Global and Planetary Change","General Earth and Planetary Sciences","Environmental Chemistry"],"status":"public","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by-nc/4.0/legalcode","image":"/images/cc_by_nc.png","name":"Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)","short":"CC BY-NC (4.0)"},"article_type":"original","type":"journal_article","_id":"9151","file_date_updated":"2021-08-11T12:23:01Z","ddc":["550"],"extern":"1","date_updated":"2022-01-24T12:26:01Z","intvolume":" 13","month":"02","scopus_import":"1","oa_version":"Published Version","abstract":[{"lang":"eng","text":"We investigate how mesoscale circulations associated with convective aggregation can modulate the sensitivity of the hydrologic cycle to warming. We quantify changes in the full distribution of rain across radiative‐convective equilibrium states in a cloud‐resolving model. For a given SST, the shift in mean rainfall between disorganized and organized states is associated with a shift in atmospheric radiative cooling, and is roughly analogous to the effect of a 4K SST increase. With rising temperatures, the increase in mean rain rate is insensitive to the presence of organization, while extremes can intensify faster in the aggregated state, leading to a faster amplification in the sporadic nature of rain. When convection aggregates, heavy rain is enhanced by 20‐30% and nonlinear behaviors are observed as a function of SST and strength of aggregation feedbacks. First, radiative‐ and surface‐flux aggregation feedbacks have multiplicative effects on extremes, illustrating a non‐trivial sensitivity to the degree of organization. Second, alternating Clausius‐Clapeyron and super‐Clausius‐Clapeyron regimes in extreme rainfall are found as a function of SST, corresponding to varying thermodynamic and dynamic contributions, and a large sensitivity to precipitation efficiency variations in some SST ranges.\r\nThe potential for mesoscale circulations in amplifying the hydrologic cycle is established. However these nonlinear distortions question the quantitative relevance of idealized self‐aggregation. This calls for a deeper investigation of relationships which capture the coupling between global energetics, aggregation feedbacks and local convection, and for systematic tests of their sensitivity to domain configurations, surface boundary conditions, microphysics and turbulence schemes."}],"issue":"2","volume":13,"language":[{"iso":"eng"}],"file":[{"content_type":"application/pdf","relation":"main_file","access_level":"open_access","success":1,"file_id":"9881","checksum":"591ce69b7a36f24346d2061ac712f0f4","file_size":1947936,"date_updated":"2021-08-11T12:23:01Z","creator":"kschuh","file_name":"2021_JAMES_Fildier.pdf","date_created":"2021-08-11T12:23:01Z"}],"publication_status":"published","publication_identifier":{"issn":["1942-2466","1942-2466"]}},{"type":"journal_article","article_type":"original","status":"public","keyword":["Materials Chemistry","Biochemistry (medical)","General Chemical Engineering","Environmental Chemistry","Biochemistry","General Chemistry"],"_id":"13359","date_updated":"2023-08-07T10:04:28Z","extern":"1","scopus_import":"1","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1016/j.chempr.2020.11.025"}],"month":"01","intvolume":" 7","abstract":[{"lang":"eng","text":"Dissipative self-assembly is ubiquitous in nature, where it gives rise to complex structures and functions such as self-healing, homeostasis, and camouflage. These phenomena are enabled by the continuous conversion of energy stored in chemical fuels, such as ATP. Over the past decade, an increasing number of synthetic chemically driven systems have been reported that mimic the features of their natural counterparts. At the same time, it has been shown that dissipative self-assembly can also be fueled by light; these optically fueled systems have been developed in parallel to the chemically fueled ones. In this perspective, we critically compare these two classes of systems. Despite the complementarity and fundamental differences between these two modes of dissipative self-assembly, our analysis reveals that multiple analogies exist between chemically and light-fueled systems. We hope that these considerations will facilitate further development of the field of dissipative self-assembly."}],"oa_version":"Published Version","issue":"1","volume":7,"publication_identifier":{"issn":["2451-9294"]},"publication_status":"published","language":[{"iso":"eng"}],"author":[{"last_name":"Weißenfels","full_name":"Weißenfels, Maren","first_name":"Maren"},{"first_name":"Julius","last_name":"Gemen","full_name":"Gemen, Julius"},{"full_name":"Klajn, Rafal","last_name":"Klajn","first_name":"Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"}],"article_processing_charge":"No","title":"Dissipative self-assembly: Fueling with chemicals versus light","citation":{"mla":"Weißenfels, Maren, et al. “Dissipative Self-Assembly: Fueling with Chemicals versus Light.” Chem, vol. 7, no. 1, Elsevier, 2021, pp. 23–37, doi:10.1016/j.chempr.2020.11.025.","ieee":"M. Weißenfels, J. Gemen, and R. Klajn, “Dissipative self-assembly: Fueling with chemicals versus light,” Chem, vol. 7, no. 1. Elsevier, pp. 23–37, 2021.","short":"M. Weißenfels, J. Gemen, R. Klajn, Chem 7 (2021) 23–37.","apa":"Weißenfels, M., Gemen, J., & Klajn, R. (2021). Dissipative self-assembly: Fueling with chemicals versus light. Chem. Elsevier. https://doi.org/10.1016/j.chempr.2020.11.025","ama":"Weißenfels M, Gemen J, Klajn R. Dissipative self-assembly: Fueling with chemicals versus light. Chem. 2021;7(1):23-37. doi:10.1016/j.chempr.2020.11.025","chicago":"Weißenfels, Maren, Julius Gemen, and Rafal Klajn. “Dissipative Self-Assembly: Fueling with Chemicals versus Light.” Chem. Elsevier, 2021. https://doi.org/10.1016/j.chempr.2020.11.025.","ista":"Weißenfels M, Gemen J, Klajn R. 2021. Dissipative self-assembly: Fueling with chemicals versus light. Chem. 7(1), 23–37."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","quality_controlled":"1","publisher":"Elsevier","oa":1,"page":"23-37","date_published":"2021-01-14T00:00:00Z","doi":"10.1016/j.chempr.2020.11.025","date_created":"2023-08-01T09:35:19Z","year":"2021","day":"14","publication":"Chem"},{"date_updated":"2022-01-24T12:28:12Z","extern":"1","article_type":"original","type":"journal_article","status":"public","keyword":["Global and Planetary Change","General Earth and Planetary Sciences","Environmental Chemistry"],"_id":"9126","issue":"8","volume":12,"publication_identifier":{"issn":["1942-2466","1942-2466"]},"publication_status":"published","language":[{"iso":"eng"}],"main_file_link":[{"open_access":"1","url":"https://doi.org/10.1029/2020MS002106"}],"month":"08","intvolume":" 12","abstract":[{"lang":"eng","text":"The goal of this study is to understand the mechanisms controlling the isotopic composition of the water vapor near the surface of tropical oceans, at the scale of about a hundred kilometers and a month. In the tropics, it has long been observed that the isotopic compositions of rain and vapor near the surface are more depleted when the precipitation rate is high. This is called the “amount effect.” Previous studies, based on observations or models with parameterized convection, have highlighted the roles of deep convective and mesoscale downdrafts and rain evaporation. But the relative importance of these processes has never been quantified. We hypothesize that it can be quantified using an analytical model constrained by large‐eddy simulations. Results from large‐eddy simulations confirm that the classical amount effect can be simulated only if precipitation rate changes result from changes in the large‐scale circulation. We find that the main process depleting the water vapor compared to the equilibrium with the ocean is the fact that updrafts stem from areas where the water vapor is more enriched. The main process responsible for the amount effect is the fact that when the large‐scale ascent increases, isotopic vertical gradients are steeper, so that updrafts and downdrafts deplete the subcloud layer more efficiently."}],"oa_version":"Published Version","author":[{"full_name":"Risi, Camille","last_name":"Risi","first_name":"Camille"},{"full_name":"Muller, Caroline J","orcid":"0000-0001-5836-5350","last_name":"Muller","id":"f978ccb0-3f7f-11eb-b193-b0e2bd13182b","first_name":"Caroline J"},{"full_name":"Blossey, Peter","last_name":"Blossey","first_name":"Peter"}],"article_processing_charge":"No","title":"What controls the water vapor isotopic composition near the surface of tropical oceans? Results from an analytical model constrained by large‐eddy simulations","citation":{"chicago":"Risi, Camille, Caroline J Muller, and Peter Blossey. “What Controls the Water Vapor Isotopic Composition near the Surface of Tropical Oceans? Results from an Analytical Model Constrained by Large‐eddy Simulations.” Journal of Advances in Modeling Earth Systems. American Geophysical Union, 2020. https://doi.org/10.1029/2020ms002106.","ista":"Risi C, Muller CJ, Blossey P. 2020. What controls the water vapor isotopic composition near the surface of tropical oceans? Results from an analytical model constrained by large‐eddy simulations. Journal of Advances in Modeling Earth Systems. 12(8), e2020MS002106.","mla":"Risi, Camille, et al. “What Controls the Water Vapor Isotopic Composition near the Surface of Tropical Oceans? Results from an Analytical Model Constrained by Large‐eddy Simulations.” Journal of Advances in Modeling Earth Systems, vol. 12, no. 8, e2020MS002106, American Geophysical Union, 2020, doi:10.1029/2020ms002106.","ama":"Risi C, Muller CJ, Blossey P. What controls the water vapor isotopic composition near the surface of tropical oceans? Results from an analytical model constrained by large‐eddy simulations. Journal of Advances in Modeling Earth Systems. 2020;12(8). doi:10.1029/2020ms002106","apa":"Risi, C., Muller, C. J., & Blossey, P. (2020). What controls the water vapor isotopic composition near the surface of tropical oceans? Results from an analytical model constrained by large‐eddy simulations. Journal of Advances in Modeling Earth Systems. American Geophysical Union. https://doi.org/10.1029/2020ms002106","short":"C. Risi, C.J. Muller, P. Blossey, Journal of Advances in Modeling Earth Systems 12 (2020).","ieee":"C. Risi, C. J. Muller, and P. Blossey, “What controls the water vapor isotopic composition near the surface of tropical oceans? Results from an analytical model constrained by large‐eddy simulations,” Journal of Advances in Modeling Earth Systems, vol. 12, no. 8. American Geophysical Union, 2020."},"user_id":"8b945eb4-e2f2-11eb-945a-df72226e66a9","article_number":"e2020MS002106","date_published":"2020-08-01T00:00:00Z","doi":"10.1029/2020ms002106","date_created":"2021-02-15T14:06:38Z","year":"2020","day":"01","publication":"Journal of Advances in Modeling Earth Systems","quality_controlled":"1","publisher":"American Geophysical Union","oa":1},{"extern":"1","date_updated":"2022-01-24T12:27:38Z","status":"public","keyword":["Global and Planetary Change","General Earth and Planetary Sciences","Environmental Chemistry"],"article_type":"original","type":"journal_article","_id":"9125","issue":"11","volume":12,"language":[{"iso":"eng"}],"publication_identifier":{"issn":["1942-2466","1942-2466"]},"publication_status":"published","month":"11","intvolume":" 12","main_file_link":[{"url":"https://doi.org/10.1029/2020MS002164","open_access":"1"}],"oa_version":"Published Version","abstract":[{"lang":"eng","text":"This study investigates the feedbacks between an interactive sea surface temperature (SST) and the self‐aggregation of deep convective clouds, using a cloud‐resolving model in nonrotating radiative‐convective equilibrium. The ocean is modeled as one layer slab with a temporally fixed mean but spatially varying temperature. We find that the interactive SST decelerates the aggregation and that the deceleration is larger with a shallower slab, consistent with earlier studies. The surface temperature anomaly in dry regions is positive at first, thus opposing the diverging shallow circulation known to favor self‐aggregation, consistent with the slower aggregation. But surprisingly, the driest columns then have a negative SST anomaly, thus strengthening the diverging shallow circulation and favoring aggregation. This diverging circulation out of dry regions is found to be well correlated with the aggregation speed. It can be linked to a positive surface pressure anomaly (PSFC), itself the consequence of SST anomalies and boundary layer radiative cooling. The latter cools and dries the boundary layer, thus increasing PSFC anomalies through virtual effects and hydrostasy. Sensitivity experiments confirm the key role played by boundary layer radiative cooling in determining PSFC anomalies in dry regions, and thus the shallow diverging circulation and the aggregation speed."}],"title":"Self‐aggregation of convective clouds with interactive sea surface temperature","author":[{"last_name":"Shamekh","full_name":"Shamekh, S.","first_name":"S."},{"orcid":"0000-0001-5836-5350","full_name":"Muller, Caroline J","last_name":"Muller","id":"f978ccb0-3f7f-11eb-b193-b0e2bd13182b","first_name":"Caroline J"},{"last_name":"Duvel","full_name":"Duvel, J.‐P.","first_name":"J.‐P."},{"full_name":"D'Andrea, F.","last_name":"D'Andrea","first_name":"F."}],"article_processing_charge":"No","user_id":"8b945eb4-e2f2-11eb-945a-df72226e66a9","citation":{"mla":"Shamekh, S., et al. “Self‐aggregation of Convective Clouds with Interactive Sea Surface Temperature.” Journal of Advances in Modeling Earth Systems, vol. 12, no. 11, e2020MS002164, American Geophysical Union, 2020, doi:10.1029/2020ms002164.","ieee":"S. Shamekh, C. J. Muller, J. ‐P. Duvel, and F. D’Andrea, “Self‐aggregation of convective clouds with interactive sea surface temperature,” Journal of Advances in Modeling Earth Systems, vol. 12, no. 11. American Geophysical Union, 2020.","short":"S. Shamekh, C.J. Muller, J. ‐P. Duvel, F. D’Andrea, Journal of Advances in Modeling Earth Systems 12 (2020).","apa":"Shamekh, S., Muller, C. J., Duvel, J. ‐P., & D’Andrea, F. (2020). Self‐aggregation of convective clouds with interactive sea surface temperature. Journal of Advances in Modeling Earth Systems. American Geophysical Union. https://doi.org/10.1029/2020ms002164","ama":"Shamekh S, Muller CJ, Duvel J ‐P., D’Andrea F. Self‐aggregation of convective clouds with interactive sea surface temperature. Journal of Advances in Modeling Earth Systems. 2020;12(11). doi:10.1029/2020ms002164","chicago":"Shamekh, S., Caroline J Muller, J.‐P. Duvel, and F. D’Andrea. “Self‐aggregation of Convective Clouds with Interactive Sea Surface Temperature.” Journal of Advances in Modeling Earth Systems. American Geophysical Union, 2020. https://doi.org/10.1029/2020ms002164.","ista":"Shamekh S, Muller CJ, Duvel J ‐P., D’Andrea F. 2020. Self‐aggregation of convective clouds with interactive sea surface temperature. Journal of Advances in Modeling Earth Systems. 12(11), e2020MS002164."},"article_number":"e2020MS002164","date_published":"2020-11-01T00:00:00Z","doi":"10.1029/2020ms002164","date_created":"2021-02-15T14:06:23Z","day":"01","publication":"Journal of Advances in Modeling Earth Systems","year":"2020","quality_controlled":"1","publisher":"American Geophysical Union","oa":1},{"title":"Diamond grows up","article_processing_charge":"No","author":[{"first_name":"Michał J.","full_name":"Białek, Michał J.","last_name":"Białek"},{"full_name":"Klajn, Rafal","last_name":"Klajn","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","first_name":"Rafal"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","citation":{"mla":"Białek, Michał J., and Rafal Klajn. “Diamond Grows Up.” Chem, vol. 5, no. 9, Elsevier, 2019, pp. 2283–85, doi:10.1016/j.chempr.2019.08.012.","ieee":"M. J. Białek and R. Klajn, “Diamond grows up,” Chem, vol. 5, no. 9. Elsevier, pp. 2283–2285, 2019.","short":"M.J. Białek, R. Klajn, Chem 5 (2019) 2283–2285.","ama":"Białek MJ, Klajn R. Diamond grows up. Chem. 2019;5(9):2283-2285. doi:10.1016/j.chempr.2019.08.012","apa":"Białek, M. J., & Klajn, R. (2019). Diamond grows up. Chem. Elsevier. https://doi.org/10.1016/j.chempr.2019.08.012","chicago":"Białek, Michał J., and Rafal Klajn. “Diamond Grows Up.” Chem. Elsevier, 2019. https://doi.org/10.1016/j.chempr.2019.08.012.","ista":"Białek MJ, Klajn R. 2019. Diamond grows up. Chem. 5(9), 2283–2285."},"date_created":"2023-08-01T09:38:38Z","date_published":"2019-09-12T00:00:00Z","doi":"10.1016/j.chempr.2019.08.012","page":"2283-2285","publication":"Chem","day":"12","year":"2019","oa":1,"quality_controlled":"1","publisher":"Elsevier","extern":"1","date_updated":"2023-08-07T10:46:50Z","keyword":["Materials Chemistry","Biochemistry (medical)","General Chemical Engineering","Environmental Chemistry","Biochemistry","General Chemistry"],"status":"public","type":"journal_article","article_type":"original","_id":"13371","volume":5,"issue":"9","language":[{"iso":"eng"}],"publication_status":"published","publication_identifier":{"issn":["2451-9308"],"eissn":["2451-9294"]},"intvolume":" 5","month":"09","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1016/j.chempr.2019.08.012"}],"scopus_import":"1","oa_version":"Published Version","abstract":[{"text":"Diamondoid nanoporous crystals represent a synthetically challenging class of materials that typically have been obtained from tetrahedral building blocks. In this issue of Chem, Stoddart and coworkers demonstrate that it is possible to generate diamondoid frameworks from a hexacationic building block lacking a tetrahedral symmetry. These results highlight the great potential of self-assembly for rapidly transforming small molecules into structurally complex functional materials.","lang":"eng"}]},{"page":"1152-1170","date_created":"2023-02-20T08:16:51Z","doi":"10.1016/j.scitotenv.2014.04.022","date_published":"2014-09-15T00:00:00Z","volume":493,"year":"2014","publication_status":"published","publication_identifier":{"issn":["0048-9697"]},"language":[{"iso":"eng"}],"publication":"Science of The Total Environment","day":"15","quality_controlled":"1","publisher":"Elsevier","scopus_import":"1","intvolume":" 493","month":"09","abstract":[{"text":"Switzerland is one of the countries with some of the longest and best glaciological data sets. Its glaciers and their changes in response to climate have been extensively investigated, and the number and quality of related studies are notable. However, a comprehensive review of glacier changes and their impact on the hydrology of glacierised catchments for Switzerland is missing and we use the opportunity provided by the EU-FP7 ACQWA project to review the current state of knowledge about past changes and future projections. We examine the type of models that have been applied to infer glacier evolution and identify knowledge gaps that should be addressed in future research in addition to those indicated in previous publications. Common characteristics in long-term series of projected future glacier runoff are an initial peak followed by a decline, associated with shifts in seasonality, earlier melt onset and reduced summer runoff. However, the quantitative predictions are difficult to compare, as studies differ in terms of model structure, calibration strategies, input data, temporal and spatial resolution as well as future scenarios used for impact studies. We identify two sources of uncertainties among those emerging from recent research, and use simulations over four glaciers to: i) quantify the importance of the correct extrapolation of air temperature, and ii) point at the key role played by debris cover in modulating glacier response.","lang":"eng"}],"oa_version":"None","article_processing_charge":"No","author":[{"id":"b28f055a-81ea-11ed-b70c-a9fe7f7b0e70","first_name":"Francesca","last_name":"Pellicciotti","full_name":"Pellicciotti, Francesca"},{"first_name":"M.","full_name":"Carenzo, M.","last_name":"Carenzo"},{"last_name":"Bordoy","full_name":"Bordoy, R.","first_name":"R."},{"first_name":"M.","full_name":"Stoffel, M.","last_name":"Stoffel"}],"title":"Changes in glaciers in the Swiss Alps and impact on basin hydrology: Current state of the art and future research","date_updated":"2023-02-24T08:36:04Z","citation":{"chicago":"Pellicciotti, Francesca, M. Carenzo, R. Bordoy, and M. Stoffel. “Changes in Glaciers in the Swiss Alps and Impact on Basin Hydrology: Current State of the Art and Future Research.” Science of The Total Environment. Elsevier, 2014. https://doi.org/10.1016/j.scitotenv.2014.04.022.","ista":"Pellicciotti F, Carenzo M, Bordoy R, Stoffel M. 2014. Changes in glaciers in the Swiss Alps and impact on basin hydrology: Current state of the art and future research. Science of The Total Environment. 493, 1152–1170.","mla":"Pellicciotti, Francesca, et al. “Changes in Glaciers in the Swiss Alps and Impact on Basin Hydrology: Current State of the Art and Future Research.” Science of The Total Environment, vol. 493, Elsevier, 2014, pp. 1152–70, doi:10.1016/j.scitotenv.2014.04.022.","ama":"Pellicciotti F, Carenzo M, Bordoy R, Stoffel M. Changes in glaciers in the Swiss Alps and impact on basin hydrology: Current state of the art and future research. Science of The Total Environment. 2014;493:1152-1170. doi:10.1016/j.scitotenv.2014.04.022","apa":"Pellicciotti, F., Carenzo, M., Bordoy, R., & Stoffel, M. (2014). Changes in glaciers in the Swiss Alps and impact on basin hydrology: Current state of the art and future research. Science of The Total Environment. Elsevier. https://doi.org/10.1016/j.scitotenv.2014.04.022","ieee":"F. Pellicciotti, M. Carenzo, R. Bordoy, and M. Stoffel, “Changes in glaciers in the Swiss Alps and impact on basin hydrology: Current state of the art and future research,” Science of The Total Environment, vol. 493. Elsevier, pp. 1152–1170, 2014.","short":"F. Pellicciotti, M. Carenzo, R. Bordoy, M. Stoffel, Science of The Total Environment 493 (2014) 1152–1170."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","extern":"1","type":"journal_article","article_type":"review","keyword":["Pollution","Waste Management and Disposal","Environmental Chemistry","Environmental Engineering"],"status":"public","_id":"12635"},{"page":"1197-1210","date_created":"2023-02-20T08:16:46Z","date_published":"2014-09-15T00:00:00Z","volume":493,"doi":"10.1016/j.scitotenv.2013.10.055","publication_status":"published","year":"2014","publication_identifier":{"issn":["0048-9697"]},"publication":"Science of The Total Environment","language":[{"iso":"eng"}],"day":"15","publisher":"Elsevier","scopus_import":"1","quality_controlled":"1","intvolume":" 493","month":"09","abstract":[{"text":"Glaciers in the Andes of Chile seem to be shrinking and possibly loosing mass, but the number and types of studies conducted, constrained mainly by data availability, are not sufficient to provide a synopsis of glacier changes for the past or future or explain in an explicit way causes of the observed changes. In this paper, we provide a systematic review of changes in glaciers for the entire country, followed by a discussion of the studies that have provided evidence of such changes. We identify a missing type of work in distributed, physically-oriented modelling studies that are needed to bridge the gap between the numerous remote sensing studies and the specific, point scale works focused on process understanding. We use an advanced mass balance model applied to one of the best monitored glaciers in the region to investigate four main research issues that should be addressed in modelling studies for a sound assessment of glacier changes: 1) the use of physically-based models of glacier ablation (energy balance models) versus more empirical models (enhanced temperature index approaches); 2) the importance of the correct extrapolation of air temperature forcing on glaciers and in high elevation areas and the large uncertainty in model outputs associated with it; 3) the role played by snow gravitational redistribution; and 4) the uncertainty associated with future climate scenarios. We quantify differences in model outputs associated with each of these choices, and conclude with suggestions for future work directions.","lang":"eng"}],"oa_version":"None","article_processing_charge":"No","author":[{"full_name":"Pellicciotti, Francesca","last_name":"Pellicciotti","first_name":"Francesca","id":"b28f055a-81ea-11ed-b70c-a9fe7f7b0e70"},{"first_name":"S.","full_name":"Ragettli, S.","last_name":"Ragettli"},{"full_name":"Carenzo, M.","last_name":"Carenzo","first_name":"M."},{"last_name":"McPhee","full_name":"McPhee, J.","first_name":"J."}],"title":"Changes of glaciers in the Andes of Chile and priorities for future work","citation":{"apa":"Pellicciotti, F., Ragettli, S., Carenzo, M., & McPhee, J. (2014). Changes of glaciers in the Andes of Chile and priorities for future work. Science of The Total Environment. Elsevier. https://doi.org/10.1016/j.scitotenv.2013.10.055","ama":"Pellicciotti F, Ragettli S, Carenzo M, McPhee J. Changes of glaciers in the Andes of Chile and priorities for future work. Science of The Total Environment. 2014;493:1197-1210. doi:10.1016/j.scitotenv.2013.10.055","ieee":"F. Pellicciotti, S. Ragettli, M. Carenzo, and J. McPhee, “Changes of glaciers in the Andes of Chile and priorities for future work,” Science of The Total Environment, vol. 493. Elsevier, pp. 1197–1210, 2014.","short":"F. Pellicciotti, S. Ragettli, M. Carenzo, J. McPhee, Science of The Total Environment 493 (2014) 1197–1210.","mla":"Pellicciotti, Francesca, et al. “Changes of Glaciers in the Andes of Chile and Priorities for Future Work.” Science of The Total Environment, vol. 493, Elsevier, 2014, pp. 1197–210, doi:10.1016/j.scitotenv.2013.10.055.","ista":"Pellicciotti F, Ragettli S, Carenzo M, McPhee J. 2014. Changes of glaciers in the Andes of Chile and priorities for future work. Science of The Total Environment. 493, 1197–1210.","chicago":"Pellicciotti, Francesca, S. Ragettli, M. Carenzo, and J. McPhee. “Changes of Glaciers in the Andes of Chile and Priorities for Future Work.” Science of The Total Environment. Elsevier, 2014. https://doi.org/10.1016/j.scitotenv.2013.10.055."},"date_updated":"2023-02-24T08:37:57Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","extern":"1","type":"journal_article","article_type":"review","keyword":["Pollution","Waste Management and Disposal","Environmental Chemistry","Environmental Engineering"],"status":"public","_id":"12634"},{"citation":{"mla":"Immerzeel, Walter Willem, et al. “Glaciers as a Proxy to Quantify the Spatial Distribution of Precipitation in the Hunza Basin.” Mountain Research and Development, vol. 32, no. 1, International Mountain Society, 2012, pp. 30–38, doi:10.1659/mrd-journal-d-11-00097.1.","apa":"Immerzeel, W. W., Pellicciotti, F., & Shrestha, A. B. (2012). Glaciers as a proxy to quantify the spatial distribution of precipitation in the Hunza basin. Mountain Research and Development. International Mountain Society. https://doi.org/10.1659/mrd-journal-d-11-00097.1","ama":"Immerzeel WW, Pellicciotti F, Shrestha AB. Glaciers as a proxy to quantify the spatial distribution of precipitation in the Hunza basin. Mountain Research and Development. 2012;32(1):30-38. doi:10.1659/mrd-journal-d-11-00097.1","short":"W.W. Immerzeel, F. Pellicciotti, A.B. Shrestha, Mountain Research and Development 32 (2012) 30–38.","ieee":"W. W. Immerzeel, F. Pellicciotti, and A. B. Shrestha, “Glaciers as a proxy to quantify the spatial distribution of precipitation in the Hunza basin,” Mountain Research and Development, vol. 32, no. 1. International Mountain Society, pp. 30–38, 2012.","chicago":"Immerzeel, Walter Willem, Francesca Pellicciotti, and Arun B. Shrestha. “Glaciers as a Proxy to Quantify the Spatial Distribution of Precipitation in the Hunza Basin.” Mountain Research and Development. International Mountain Society, 2012. https://doi.org/10.1659/mrd-journal-d-11-00097.1.","ista":"Immerzeel WW, Pellicciotti F, Shrestha AB. 2012. Glaciers as a proxy to quantify the spatial distribution of precipitation in the Hunza basin. Mountain Research and Development. 32(1), 30–38."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","article_processing_charge":"No","author":[{"last_name":"Immerzeel","full_name":"Immerzeel, Walter Willem","first_name":"Walter Willem"},{"first_name":"Francesca","id":"b28f055a-81ea-11ed-b70c-a9fe7f7b0e70","full_name":"Pellicciotti, Francesca","last_name":"Pellicciotti"},{"last_name":"Shrestha","full_name":"Shrestha, Arun B.","first_name":"Arun B."}],"title":"Glaciers as a proxy to quantify the spatial distribution of precipitation in the Hunza basin","oa":1,"quality_controlled":"1","publisher":"International Mountain Society","year":"2012","publication":"Mountain Research and Development","day":"01","page":"30-38","date_created":"2023-02-20T08:17:52Z","date_published":"2012-02-01T00:00:00Z","doi":"10.1659/mrd-journal-d-11-00097.1","_id":"12647","type":"journal_article","article_type":"original","keyword":["General Environmental Science","Development","Environmental Chemistry"],"status":"public","date_updated":"2023-02-21T08:56:29Z","extern":"1","abstract":[{"text":"Accurate quantification of the spatial distribution of precipitation in mountain regions is crucial for assessments of water resources and for the understanding of high-altitude hydrology, yet it is one of the largest unknowns due to the lack of high-altitude observations. The Hunza basin in Pakistan contains very large glacier systems, which, given the melt, cannot persist unless precipitation (snow input) is much higher than what is observed at the meteorological stations, mostly located in mountain valleys. Several studies, therefore, suggest strong positive vertical precipitation lapse rates; in the present study, we quantify this lapse rate by using glaciers as a proxy. We assume a neutral mass balance for the glaciers for the period from 2001 to 2003, and we inversely model the precipitation lapse by balancing the total accumulation in the catchment area and the ablation over the glacier area for the 50 largest glacier systems in the Hunza basin in the Karakoram. Our results reveal a vertical precipitation lapse rate that equals 0.21 ± 0.12% m−1, with a maximum precipitation at an elevation of 5500 masl. We showed that the total annual basin precipitation (828 mm) is 260% higher than what is estimated based on interpolated observations (319 mm); this has major consequences for hydrological modeling and water resource assessments in general. Our results were validated by using previously published studies on individual glaciers as well as the water balance of the Hunza basin. The approach is more widely applicable in mountain ranges where precipitation measurements at high altitude are lacking.","lang":"eng"}],"oa_version":"Published Version","main_file_link":[{"url":"https://doi.org/10.1659/MRD-JOURNAL-D-11-00097.1","open_access":"1"}],"scopus_import":"1","intvolume":" 32","month":"02","publication_status":"published","publication_identifier":{"issn":["0276-4741"],"eissn":["1994-7151"]},"language":[{"iso":"eng"}],"issue":"1","volume":32}]