---
_id: '8361'
abstract:
- lang: eng
text: With the lithium-ion technology approaching its intrinsic limit with graphite-based
anodes, Li metal is recently receiving renewed interest from the battery community
as potential high capacity anode for next-generation rechargeable batteries. In
this focus paper, we review the main advances in this field since the first attempts
in the mid-1970s. Strategies for enabling reversible cycling and avoiding dendrite
growth are thoroughly discussed, including specific applications in all-solid-state
(inorganic and polymeric), Lithium–Sulfur (Li–S) and Lithium-O2 (air) batteries.
A particular attention is paid to recent developments of these battery technologies
and their current state with respect to the 2030 targets of the EU Integrated
Strategic Energy Technology Plan (SET-Plan) Action 7.
acknowledgement: A.V. and K.T. acknowledge, respectively, the financial support of
the Helmholtz Association and BMW AG. J.H. acknowledges the collabo-ration project
“Accordo di Collaborazione Quadro 2015” between Uni-versity of Ferrara (Department
of Chemical and Pharmaceutical Sciences) and Sapienza University of Rome (Department
of Chemistry). S.D., H.A. and S.K. thank the Fraunhofer Gesellschaft, Technische
Uni-versit ̈at Dresden and would like to acknowledge European Union’s Horizon
2020 research and innovation programme under grant agree-ment No 814471. S.A.F.
and C.P. are indebted to the European Research Council (ERC) under the European
Union’s Horizon 2020 research and innovation program (grant agreement no. 636069)
and IST Austria.
article_number: '228803'
article_processing_charge: No
article_type: original
author:
- first_name: Alberto
full_name: Varzi, Alberto
last_name: Varzi
orcid: 0000-0001-5069-0589
- first_name: Katharina
full_name: Thanner, Katharina
last_name: Thanner
orcid: 0000-0001-5394-2323
- first_name: Roberto
full_name: Scipioni, Roberto
last_name: Scipioni
orcid: 0000-0003-1926-421X
- first_name: Daniele
full_name: Di Lecce, Daniele
last_name: Di Lecce
- first_name: Jusef
full_name: Hassoun, Jusef
last_name: Hassoun
- first_name: Susanne
full_name: Dörfler, Susanne
last_name: Dörfler
- first_name: Holger
full_name: Altheus, Holger
last_name: Altheus
- first_name: Stefan
full_name: Kaskel, Stefan
last_name: Kaskel
- first_name: Christian
full_name: Prehal, Christian
last_name: Prehal
orcid: 0000-0003-0654-0940
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
citation:
ama: Varzi A, Thanner K, Scipioni R, et al. Current status and future perspectives
of lithium metal batteries. Journal of Power Sources. 2020;480(12). doi:10.1016/j.jpowsour.2020.228803
apa: Varzi, A., Thanner, K., Scipioni, R., Di Lecce, D., Hassoun, J., Dörfler, S.,
… Freunberger, S. A. (2020). Current status and future perspectives of lithium
metal batteries. Journal of Power Sources. Elsevier. https://doi.org/10.1016/j.jpowsour.2020.228803
chicago: Varzi, Alberto, Katharina Thanner, Roberto Scipioni, Daniele Di Lecce,
Jusef Hassoun, Susanne Dörfler, Holger Altheus, Stefan Kaskel, Christian Prehal,
and Stefan Alexander Freunberger. “Current Status and Future Perspectives of Lithium
Metal Batteries.” Journal of Power Sources. Elsevier, 2020. https://doi.org/10.1016/j.jpowsour.2020.228803.
ieee: A. Varzi et al., “Current status and future perspectives of lithium
metal batteries,” Journal of Power Sources, vol. 480, no. 12. Elsevier,
2020.
ista: Varzi A, Thanner K, Scipioni R, Di Lecce D, Hassoun J, Dörfler S, Altheus
H, Kaskel S, Prehal C, Freunberger SA. 2020. Current status and future perspectives
of lithium metal batteries. Journal of Power Sources. 480(12), 228803.
mla: Varzi, Alberto, et al. “Current Status and Future Perspectives of Lithium Metal
Batteries.” Journal of Power Sources, vol. 480, no. 12, 228803, Elsevier,
2020, doi:10.1016/j.jpowsour.2020.228803.
short: A. Varzi, K. Thanner, R. Scipioni, D. Di Lecce, J. Hassoun, S. Dörfler, H.
Altheus, S. Kaskel, C. Prehal, S.A. Freunberger, Journal of Power Sources 480
(2020).
date_created: 2020-09-10T10:48:40Z
date_published: 2020-12-31T00:00:00Z
date_updated: 2023-08-22T09:20:37Z
day: '31'
department:
- _id: StFr
doi: 10.1016/j.jpowsour.2020.228803
external_id:
isi:
- '000593857300001'
intvolume: ' 480'
isi: 1
issue: '12'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.1016/j.jpowsour.2020.228803
month: '12'
oa: 1
oa_version: Published Version
publication: Journal of Power Sources
publication_identifier:
issn:
- 0378-7753
publication_status: published
publisher: Elsevier
quality_controlled: '1'
related_material:
record:
- id: '8067'
relation: earlier_version
status: public
status: public
title: Current status and future perspectives of lithium metal batteries
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 480
year: '2020'
...
---
_id: '7298'
abstract:
- lang: eng
text: Lithium-ion batteries are in widespread use in electric vehicles and hybrid
vehicles. Besides features like energy density, cost, lifetime, and recyclability
the safety of a battery system is of prime importance. The separator material
impacts all these properties and requires therefore an informed selection. The
interplay between the mechanical and electrochemical properties as key selection
criteria is investigated. Mechanical properties were investigated using tensile
and puncture penetration tests at abuse relevant conditions. To investigate the
electrochemical performance in terms of effective conductivity a method based
on impedance spectroscopy was introduced. This methodology is applied to evaluate
ten commercial separators which allows for a trade-off analysis of mechanical
versus electrochemical performance. Based on the results, and in combination with
other factors, this offers an effective approach to select suitable separators
for automotive applications.
article_processing_charge: No
article_type: original
author:
- first_name: Martin
full_name: Plaimer, Martin
last_name: Plaimer
- first_name: Christoph
full_name: Breitfuß, Christoph
last_name: Breitfuß
- first_name: Wolfgang
full_name: Sinz, Wolfgang
last_name: Sinz
- first_name: Simon F.
full_name: Heindl, Simon F.
last_name: Heindl
- first_name: Christian
full_name: Ellersdorfer, Christian
last_name: Ellersdorfer
- first_name: Hermann
full_name: Steffan, Hermann
last_name: Steffan
- first_name: Martin
full_name: Wilkening, Martin
last_name: Wilkening
- first_name: Volker
full_name: Hennige, Volker
last_name: Hennige
- first_name: Reinhard
full_name: Tatschl, Reinhard
last_name: Tatschl
- first_name: Alexander
full_name: Geier, Alexander
last_name: Geier
- first_name: Christian
full_name: Schramm, Christian
last_name: Schramm
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
citation:
ama: 'Plaimer M, Breitfuß C, Sinz W, et al. Evaluating the trade-off between mechanical
and electrochemical performance of separators for lithium-ion batteries: Methodology
and application. Journal of Power Sources. 2016;306(2):702-710. doi:10.1016/j.jpowsour.2015.12.047'
apa: 'Plaimer, M., Breitfuß, C., Sinz, W., Heindl, S. F., Ellersdorfer, C., Steffan,
H., … Freunberger, S. A. (2016). Evaluating the trade-off between mechanical and
electrochemical performance of separators for lithium-ion batteries: Methodology
and application. Journal of Power Sources. Elsevier. https://doi.org/10.1016/j.jpowsour.2015.12.047'
chicago: 'Plaimer, Martin, Christoph Breitfuß, Wolfgang Sinz, Simon F. Heindl, Christian
Ellersdorfer, Hermann Steffan, Martin Wilkening, et al. “Evaluating the Trade-off
between Mechanical and Electrochemical Performance of Separators for Lithium-Ion
Batteries: Methodology and Application.” Journal of Power Sources. Elsevier,
2016. https://doi.org/10.1016/j.jpowsour.2015.12.047.'
ieee: 'M. Plaimer et al., “Evaluating the trade-off between mechanical and
electrochemical performance of separators for lithium-ion batteries: Methodology
and application,” Journal of Power Sources, vol. 306, no. 2. Elsevier,
pp. 702–710, 2016.'
ista: 'Plaimer M, Breitfuß C, Sinz W, Heindl SF, Ellersdorfer C, Steffan H, Wilkening
M, Hennige V, Tatschl R, Geier A, Schramm C, Freunberger SA. 2016. Evaluating
the trade-off between mechanical and electrochemical performance of separators
for lithium-ion batteries: Methodology and application. Journal of Power Sources.
306(2), 702–710.'
mla: 'Plaimer, Martin, et al. “Evaluating the Trade-off between Mechanical and Electrochemical
Performance of Separators for Lithium-Ion Batteries: Methodology and Application.”
Journal of Power Sources, vol. 306, no. 2, Elsevier, 2016, pp. 702–10,
doi:10.1016/j.jpowsour.2015.12.047.'
short: M. Plaimer, C. Breitfuß, W. Sinz, S.F. Heindl, C. Ellersdorfer, H. Steffan,
M. Wilkening, V. Hennige, R. Tatschl, A. Geier, C. Schramm, S.A. Freunberger,
Journal of Power Sources 306 (2016) 702–710.
date_created: 2020-01-15T12:16:51Z
date_published: 2016-02-29T00:00:00Z
date_updated: 2021-01-12T08:12:51Z
day: '29'
doi: 10.1016/j.jpowsour.2015.12.047
extern: '1'
intvolume: ' 306'
issue: '2'
language:
- iso: eng
month: '02'
oa_version: None
page: 702-710
publication: Journal of Power Sources
publication_identifier:
issn:
- 0378-7753
publication_status: published
publisher: Elsevier
quality_controlled: '1'
status: public
title: 'Evaluating the trade-off between mechanical and electrochemical performance
of separators for lithium-ion batteries: Methodology and application'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 306
year: '2016'
...
---
_id: '7327'
abstract:
- lang: eng
text: "Propagation of performance changes to adjacent cells in polymer electrolyte
fuel cell stacks is studied by means of voltage monitoring and local current density
measurements in peripheral cells of the stack. A technical fuel cell stack has
been modified by implementing two independent reactant and coolant supplies in
order to deliberately change the performance of one cell (anomalous cell) and
study the coupling phenomena to adjacent cells (coupling cells), while keeping
the working conditions of the later cell-group unaltered.\r\nTwo anomalies are
studied: (i) air starvation and (ii) thermal anomaly, in a single anomalous cell
in the stack and their coupling to adjacent cells. The results have shown that
anomalies inducing considerable changes in the local current density of the anomalous
cell (such as air starvation) propagate to adjacent cells affecting their performance.
The propagation of local current density changes takes place via the common bipolar
plate due to its finite thickness and in-plane conductivity. Consequently, anomalies
which do not strongly influence the local current density distribution (such as
a thermal anomaly under the studied working conditions) do not propagate to adjacent
cells."
article_processing_charge: No
article_type: original
author:
- first_name: Marco
full_name: Santis, Marco
last_name: Santis
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Matthias
full_name: Papra, Matthias
last_name: Papra
- first_name: Alexander
full_name: Wokaun, Alexander
last_name: Wokaun
- first_name: Felix N.
full_name: Büchi, Felix N.
last_name: Büchi
citation:
ama: Santis M, Freunberger SA, Papra M, Wokaun A, Büchi FN. Experimental investigation
of coupling phenomena in polymer electrolyte fuel cell stacks. Journal of Power
Sources. 2006;161(2):1076-1083. doi:10.1016/j.jpowsour.2006.06.007
apa: Santis, M., Freunberger, S. A., Papra, M., Wokaun, A., & Büchi, F. N. (2006).
Experimental investigation of coupling phenomena in polymer electrolyte fuel cell
stacks. Journal of Power Sources. Elsevier. https://doi.org/10.1016/j.jpowsour.2006.06.007
chicago: Santis, Marco, Stefan Alexander Freunberger, Matthias Papra, Alexander
Wokaun, and Felix N. Büchi. “Experimental Investigation of Coupling Phenomena
in Polymer Electrolyte Fuel Cell Stacks.” Journal of Power Sources. Elsevier,
2006. https://doi.org/10.1016/j.jpowsour.2006.06.007.
ieee: M. Santis, S. A. Freunberger, M. Papra, A. Wokaun, and F. N. Büchi, “Experimental
investigation of coupling phenomena in polymer electrolyte fuel cell stacks,”
Journal of Power Sources, vol. 161, no. 2. Elsevier, pp. 1076–1083, 2006.
ista: Santis M, Freunberger SA, Papra M, Wokaun A, Büchi FN. 2006. Experimental
investigation of coupling phenomena in polymer electrolyte fuel cell stacks. Journal
of Power Sources. 161(2), 1076–1083.
mla: Santis, Marco, et al. “Experimental Investigation of Coupling Phenomena in
Polymer Electrolyte Fuel Cell Stacks.” Journal of Power Sources, vol. 161,
no. 2, Elsevier, 2006, pp. 1076–83, doi:10.1016/j.jpowsour.2006.06.007.
short: M. Santis, S.A. Freunberger, M. Papra, A. Wokaun, F.N. Büchi, Journal of
Power Sources 161 (2006) 1076–1083.
date_created: 2020-01-15T12:22:56Z
date_published: 2006-10-27T00:00:00Z
date_updated: 2021-01-12T08:13:06Z
day: '27'
doi: 10.1016/j.jpowsour.2006.06.007
extern: '1'
intvolume: ' 161'
issue: '2'
language:
- iso: eng
month: '10'
oa_version: None
page: 1076-1083
publication: Journal of Power Sources
publication_identifier:
issn:
- 0378-7753
publication_status: published
publisher: Elsevier
status: public
title: Experimental investigation of coupling phenomena in polymer electrolyte fuel
cell stacks
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 161
year: '2006'
...